1424372-91-7Relevant academic research and scientific papers
PHOSPHINE COMPOUND HAVING PERFLUORO GROUP, AND COMPLEX BETWEEN METAL AND PHOSPHINE HAVING PERFLUORO GROUP
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, (2018/10/16)
PROBLEM TO BE SOLVED: To provide a perfluoroalkylphosphine compound, and a complex between a metal and the perfluoroalkylphosphine. SOLUTION: A perfluoroalkylphosphine compound is a phosphine compound represented by the general formula Rf-PR1R2. In the formula, R1 and R2 are each independently a substituted or unsubstituted hydrocarbon group; Rf is a perfluorinated hydrocarbon group. Also provided is a complex between the perfluoroalkylphosphine and a phosphine coordination metal. SELECTED DRAWING: None COPYRIGHT: (C)2016,JPOandINPIT
METHODS OF PRODUCING PHOSPHINE COMPOUND HAVING PERFLUORO GROUP AND COMPLEX BETWEEN METAL AND PHOSPHINE HAVING PERFLUORO GROUP
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, (2018/10/19)
PROBLEM TO BE SOLVED: To provide methods of producing a perfluoroalkylphosphine compound improved in a phosphorus element yield and a chemical yield. SOLUTION: A method of producing a perfluoroalkylphosphine compound comprises either reacting a perfluoroalkyl iodide with, e.g., 2,4,6-trimethylbenzoyldiphenylphosphine oxide (TMDPO) or a triarylphosphine such as triphenylphosphine, which are easily available, in the presence of a radical generator such as azobis(isobutyronitrile) or light irradiation, or reacting TMDPO or the like with perfluoroalkyl iodide in the presence of diphenylphosphine, diethylphosphine, dicyclohexylphosphine or the like. SELECTED DRAWING: None COPYRIGHT: (C)2016,JPOandINPIT
Synthesis and properties of perfluoroalkyl phosphine ligands: Photoinduced reaction of diphosphines with perfluoroalkyl iodides
Kawaguchi, Shin-Ichi,Minamida, Yoshiaki,Ohe, Takashi,Nomoto, Akihiro,Sonoda, Motohiro,Ogawa, Akiya
, p. 1748 - 1752 (2013/04/10)
A 'F'lurry of activity: The title reaction provides a convenient procedure for direct synthesis of perfluoroalkylated phosphines. The synthesized phosphine n-C10F21PPh2 forms a complex with palladium(II) to give 1 and several runs of coupling reactions are attained with n-C10F21PPh2 by using a fluorous/organic biphasic system. Copyright
