142472-05-7Relevant articles and documents
Biomimetic Asymmetric Reduction of Tetrasubstituted Olefin 2,3-Disubstituted Inden-1-ones with Chiral and Regenerable NAD(P)H Model CYNAM
Ding, Yi-Xuan,Wu, Bo,Zhou, Yong-Gui,Zhu, Zhou-Hao
supporting information, p. 7166 - 7170 (2021/09/22)
Because of the formidable development of the asymmetric reduction of tetrasubstituted olefins, an effective method is in urgent demand. Herein, through the biomimetic protocol of the coenzyme NAD(P)H, the reduction of tetrasubstituted olefin 2,3-substitut
A rapid and efficient access to diaryldibenzo[b,f][1,5]diazocines
Wang, Xiao,Li, Jianzhong,Zhao, Na,Wan, Xiaobo
supporting information; experimental part, p. 709 - 711 (2011/04/24)
2-Benzoylbenzoyl azides undergo facile cyclization under acidic conditions to give substituted dibenzo[b,f][1,5]-diazocines in good yields. This approach shortens the synthetic steps toward these compounds as compared with conventional methods. The mechanism of the diazocine synthesis is assumed to proceed by an unprecedented intermolecular [2 + 2] cyclization.