14252-16-5

Usage

InChI:InChI=1/C18H20O/c1-13-7-5-6-8-16(13)17(19)14-9-11-15(12-10-14)18(2,3)4/h5-12H,1-4H3

Upstream product

• 201230-82-2 carbon monoxide 
• 16419-60-6 2-Methylphenylboronic acid 
• 52436-75-6 (4-tert-butylphenyl)diazonium tetrafluoroborate 
• 253185-03-4 tert-butylbenzene 
• 933-88-0 ortho-toluoyl chloride 
• 615-37-2 ortho-methylphenyl iodide 
• 70663-11-5 1-(4-(tert-butyl) benzyl)-2-methylbenzene 
• 63488-10-8 4-tert-butylmagnesium bromide 
• 130250-61-2 2-methyl-N-methoxy-N-methylbenzamide 
• 118-90-1 ortho-methylbenzoic acid 
• 95-46-5 2-methylphenyl bromide 
• 1710-98-1 p-tert-butyl benzoyl chloride 

Downstream Products

• 870105-28-5 1-(4-tert-butylphenyl)naphthalene-2,3-dicarboxylic acid imide 
• 870105-29-6 4-(4-tert-butyl-phenyl)-2-phenyl-benzo[f]isoindole-1,3-dione 

Relevant academic research and scientific papers

Cercosporin-bioinspired selective photooxidation reactions under mild conditions

The development of an efficient system for selective oxidation of organic compounds to generate more valuable compounds with molecular oxygen is a significant challenge in industrial chemistry. Bioinspired by the ability of naturally occurring perylenequinonoid pigments (PQPs) to generate reactive oxygen species (ROS) upon photoirradiation, here we report that cercosporin, one of the perylenequinonoid pigments, can function as a cost-effective and environmentally friendly photocatalyst for a wide range of selective oxidations, including benzylic C-H bonds to carbonyls, amines to aldehydes, and sulfides to sulfoxides. All of the representative reactions proceeded smoothly with high efficiency under mild conditions. Owing to the use of inexpensive metal-free visible light-driven photocatalyst produced from microbial fermentation with cheap glucose as the starting material and the ease of handling, we expect that this developed method will be particularly attractive for many more applications in synthetic transformation.

Light-Driven Carboxylation of o-Alkylphenyl Ketones with CO2

o-Alkylphenyl ketones undergo a C-C bond forming carboxylation reaction with CO2 simply upon irradiation with UV light or even solar light. The reaction presents a clean process exploiting light energy as the driving force for carboxylation of organic molecules with CO2.

Transition-metal-free, ambient-pressure carbonylative cross-coupling reactions of aryl halides with potassium aryltrifluoroborates

We disclose an unprecedented transition-metal-free carbonylative cross coupling of aryl halides with potassium aryl trifluoroborates even at atmospheric pressure of carbon monoxide. This protocol is efficient, operationally simple, and shows wide scope with regard to both aryl halides and potassium aryl trifluoroborates containing a series of active functional groups.

Phthalocyanines and related compounds: XXXIX. Synthesis of derivatives of some substituted 1-phenylnaphthalene-2,3-dicarboxylic acids

Derivatives (dinitriles, anhydrides, imides, N-phenylimides) of substituted 1-phenylnaphthalene-2,3-dicarboxylic and 1-phenylphenanthrene-2,3-dicarboxylic acids were prepared by the reactions of 2-bromomethylbenzophenones with various dienophiles. Starting from these derivatives, gallium complexes of substituted tetra-1-phenyl-2,3-naphthalocyanines and tetra(1-phenyl-2,3-phenanthro) porphyrazine were synthesized. 2005 Pleiades Publishing, Inc.

Palladium-imidazolium-catalyzed carbonylative coupling of aryl diazonium ions and aryl boronic acids

Palladium(II) acetate and N,N-bis-(2,6-diisopropylphenyl)dihydroimidazolium chloride (2 mol%) were used to catalyze the carbonylative coupling of aryl diazonium tetrafluoroborate salts and aryl boronic acids to form aryl ketones. Optimal conditions includ