1425471-48-2

Upstream product

• 1425471-45-9 p-iodophenyl 2,3-O-isopropylidene-α-L-rhamnopyranoside 
• 100-39-0 benzyl bromide 
• 1425471-42-6 p-iodophenyl 2,3,4-tri-O-acetyl-α-L-rhamnopyranoside 
• 7404-35-5 1,2,3,4-tetra-O-acetyl-L-rhamnopyranose 

Downstream Products

• 1425471-51-7 p-iodophenyl 4-O-benzyl-α-L-rhamnopyranoside 
• 1425471-76-6 p-iodophenyl (3-O-allyl-2-O-benzoyl-4-O-benzyl-α-L-rhamnopyranosyl)-(1→3)-(4-O-benzyl-2-O-methyl)-α-L-rhamnopyranoside 
• 1425471-79-9 (3-O-allyl-4-O-benzyl-α-L-rhamnopyranosyl)-(1→3)-p-iodophenyl 2-O-methyl-4-O-benzyl-α-L-rhamnopyranoside 
• 1425471-82-4 (2-O-benzyl-3-O-allyl-4-O-benzyl-α-L-rhamnopyranosyl)-(1→3)-p-iodophenyl 2-O-methyl-4-O-benzyl-α-L-rhamnopyranoside 
• 1425471-85-7 (2,4-di-O-benzyl-α-L-rhamnopyranosyl)-(1→3)-p-iodophenyl 2-O-methyl-4-O-benzyl-α-L-rhamnopyranoside 
• 1425471-88-0 p-iodophenyl (3,4-di-O-acetyl-2-O-methyl-α-L-fucopyranosyl)-(1→3)-(2,4-di-O-benzyl-α-L-rhamnopyranosyl)-(1→3)-(4-O-benzyl-2-O-methyl)-α-L-rhamnopyranoside 
• 1425471-91-5 C₄₇H₅₇IO₁₃ 

Relevant academic research and scientific papers

Total synthesis of the triglycosyl phenolic glycolipid PGL-tb1 from mycobacterium tuberculosis

Complex: The synthesis of the glycolipid PGL-tb1 present in the outer membrane of hypervirulent strains of Mycobacterium tuberculosis has been accomplished for the first time by using a highly convergent strategy featuring a Sonogashira coupling to unite a phenolic trisaccharide with the phthiocerol. Efficient asymmetric Cu-catalyzed 1,4-additions to unsaturated thioesters and cyclic enones have been employed to introduce the methyl groups. Copyright