1426147-48-9

Upstream product

• 3282-30-2 pivaloyl chloride 
• 20638-61-3 (4S,5R)-4-(hydroxymethyl)-2-phenyl-1,3-dioxan-5-ol 
• 1426147-60-5 C₁₆H₂₂O₅ 
• 106-95-6 allyl bromide 

Relevant academic research and scientific papers

Application of a stereoselective rhodium(II)-catalyzed oxonium ylide formation-[2,3]-sigmatropic rearrangement of an α-diazo-β-keto ester to the synthesis of 2-epi-cinatrin C1 dimethyl ester

The Rh2(OAc)4-catalyzed oxonium ylide formation-[2,3]-sigmatropic rearrangement of a highly functionalized α-diazo-β-keto ester derived from d-glucose proceeded stereoselectively to give the corresponding tetrahydrofuran-3-one as a single diastereomer in high yield. This reaction was applied to the synthesis of 2-epi-cinatrin C1 dimethyl ester as a key step. Georg Thieme Verlag Stuttgart · New York.