14266-60-5

Usage

Uses

Used in Chemical Synthesis:
(6Z)-6-[(phenylamino)methylidene]cyclohexa-2,4-dien-1-one nickel (2:1) is used as a catalyst for promoting chemical transformations in the chemical synthesis industry. Its application is crucial in the coupling of organic molecules and the formation of carbon-carbon bonds, which are fundamental processes in creating complex organic compounds.
Used in Pharmaceutical Industry:
In the pharmaceutical industry, (6Z)-6-[(phenylamino)methylidene]cyclohexa-2,4-dien-1-one nickel (2:1) is utilized as a catalyst for the synthesis of complex drug molecules. Its ability to mediate reduction and oxidation reactions allows for the efficient production of various pharmaceutical compounds, contributing to the development of new medications and therapies.
Used in Material Science:
(6Z)-6-[(phenylamino)methylidene]cyclohexa-2,4-dien-1-one nickel (2:1) is also employed in the material science field, where it serves as a catalyst for the synthesis of novel materials with specific properties. These materials can be used in various applications, such as electronics, energy storage, and advanced coatings.
Used in Environmental Applications:
In the environmental sector, (6Z)-6-[(phenylamino)methylidene]cyclohexa-2,4-dien-1-one nickel (2:1) can be used as a catalyst for the degradation of pollutants and contaminants. Its catalytic properties enable the conversion of harmful substances into less toxic or more easily removable forms, thus contributing to environmental remediation efforts.
Overall, (6Z)-6-[(phenylamino)methylidene]cyclohexa-2,4-dien-1-one nickel (2:1) is a versatile and essential compound in the fields of organic chemistry, pharmaceuticals, material science, and environmental applications, thanks to its unique catalytic properties and ability to mediate various chemical reactions.

Upstream product

• 81010-33-5 Ni(N-Ph-salam)2(Py)2 
• 15379-71-2 bis(salicylaldehyde)-nickel(II)-dihydrate 
• 779-84-0 N-phenylsalicylaldimine 
• 6018-89-9 nickel(II) acetate tetrahydrate 
• 14266-60-5 bis(N-phenylsalicylideneaminato)nickel(II) 
• 38929-70-3 bis(N-phenylsalicylideneaminato)nickel(II) 
• 62-53-3 aniline 
• 373-02-4 nickel diacetate 
• 90-02-8 salicylaldehyde 
• 36339-86-3 bis(3,6-dimethylsalicylaldehydato)nickel(II) 
• 7440-02-0 nickel 

Downstream Products

• 14283-99-9 bis(N-salicylaldimino)nickel(II) 
• 142-04-1 aniline hydrochloride 
• 3117-61-1 2-(iminomethyl)phenol 
• 14701-22-5 nickel(II) 
• 3291-00-7 2-(hydrazonomethyl)phenol 
• 1160-76-5 salicylaldehyde 2,4-dinitrophenylhydrazone 
• 779-84-0 N-phenylsalicylaldimine 
• 78199-16-3 [Ni(ps)(NO₃)(2-pic)]2*2CH₂Cl₂ 
• 80315-61-3 (OC₆H₄CHNC₆H₅)2Ni(C₅H₅N)2 
• 14266-60-5 bis(N-phenylsalicylideneaminato)nickel(II) 
• 38929-70-3 bis(N-phenylsalicylideneaminato)nickel(II) 
• 81010-33-5 Ni(N-Ph-salam)2(Py)2 
• 5601-32-1 diphenyl(N-phenylsalicylaldiminato)boron 
• 54515-04-7 [Ni(II)(salicylaldehyde oximate)2] 

Relevant academic research and scientific papers

Influence of ferrocene and transition metals on the biological activities of Schiff bases

A series of organic and organometallic Schiff bases bearing phenylferrocene and their six transition metal complexes have been prepared and tested for their potential biological applications by using antifungal, antibacterial, antitumor activities, toxici

Synthesis, characterization and crystal structure studies of nickel(II) complexes with NO donor schiff base ligands

Four complexes of the type [Ni(N-substituted-salicydenaminato) 2], with bidentate Schiff base ligands (L1-L4), have been synthesized. The complexes were characterized by IR and elemental analysis methods. The solid state s

Steric and conformational effects on the kinetics of ligand substitution in bis(salicylaldiminato)nickel(II) complexes

Stopped-flow spectrophotometry has been used to study the kinetics of ligand substitution in bis(N-R-salicylaldiminato)nickel(II) complexes I (R = Et, i-Pr, t-Bu) by bidentate ligands HB (acetylacetone, benzoylacetone, dibenzoylmethane, trifluoroacetylacetone, 8-hydroxyquinoline, N-ethylsalicylaldimine) in methanol, 2-propanol, and toluene. A two-term rate law, rate = (kS + kHB[HB])[complex], has been found. The substitution of the first ligand in I is rate determining. Rate constant kS, describing the solvent path, and the corresponding activation parameters ΔH≠ and ΔS≠ do not depend on the nature of the entering ligand for I with R = t-Bu studied in methanol. Rate constant kHB is strongly dependent on the nature of the entering ligand HB. The relative contributions of the two pathways to the overall rate are governed by the conformational equilibrium planar ? tetrahedral of complexes I: the planar isomer favors the ligand-dependent path kHB and the tetrahedral one the solvent path kS. For both pathways mechanisms are derived, which have in common the rate-determining rupture of the Ni-O bond. They differ in that the solvent path is initiated by the attack of an alcohol molecule at the donor oxygen of a coordinated ligand through hydrogen bonding, whereas ligand attack occurs at the metal. The factors influencing the ligand path are the donor ability, acid strength, and stereochemical properties of the entering ligand as well as the Lewis acidity of the substrate. The discussion focuses on a comparison of the nickel system studied with corresponding copper(II) systems and with ligand substitution in square-planar d8 complexes. Additional kinetic information is presented from studies carried out in the solvent mixtures toluene/methanol and toluene/pyridine. The equilibrium constant for the addition of pyridine to complexes I (R = Et, n-Pr, i-Pr, allyl, n-Bu, i-Bu, t-Bu, phenyl) has been determined spectrophotometrically in toluene at 298 K. The individual equilibrium constants for the formation of the mono- (K1) and bis(pyridine) (K2) adduct were calculated (K1 ? K2). The effect of the conformational equilibrium and of self-association on K1 and K2 is discussed.

Kinetics of Thermal Pyridine Dissociation of Ni(N-arylsalicylideneaminato)2(pyridine)2 in Solid Phase

The kinetics of the thermal pyridine dissociation reactions of Ni2py2, where R=H(1), p-F(2), p-CH3O(3), p-CH3(4), p-Cl(5), and p-Br(6), in solid phase, were analyzed by the isothermal weight-loss measurements. On pyrolysis, these pyridine

Kinetics of Monomerization or Polymerization Reaction for Bis(N-phenyl-salicylideneaminato)nickel(II) and Bis(N-methylsalicylideneaminato)nickel(II) in Solid Phase

A kinetic investigation was carried out by means of a thermomagnetic analysis on two structural transformation reactions in solid phase: monomeric square planar-to-polymeric octahedral for Ni(N-Me-salam)2 and polymeric octahedral-to-monomeric square planar for Ni(N-Ph-salam)2.The polymerization process followed the Avrami-Erofeev equation (n=2) with Ea=303 kJ/mol and the monomerization followed the first order equation with Ea=78 kJ/mol.The thermal pyridine liberating reaction of Ni(N-Ph-salam)2py2, involving an octahedral-to-square planar transformation, has beeninvestigated isothermally found to follow the first order equation with Ea=167 kJ/mol.

Formation of Coordination Compounds under Model Conditions of Frictional Contact

The model used was simultaneous thermal vaporisation in a vacuum of metals and active components of lubricants.Compounds are formed identical with those obtained under conditions of limiting friction.The mechanism of the formation of coordination compounds during friction involves local temperatures above 1000 deg C.