1427180-83-3

Upstream product

• 100-07-2 4-methoxy-benzoyl chloride 
• 1293990-75-6 N-tert-pentanoyloxy-p-methoxybenzamide 
• 623-00-7 4-bromobenzenecarbonitrile 
• 1427180-54-8 tetrabutylammonium 4-trifluoroborato-6-methoxy-3,4-dihydroisoquinolin-1(2H)-one 

Relevant academic research and scientific papers

Complementary regioselectivity in Rh(III)-catalyzed insertions of potassium vinyltrifluoroborate via C-H activation: Preparation and use of 4-trifluoroboratotetrahydroisoquinolones

Potassium vinyltrifluoroborate was found to be an efficient partner with benzamide derivatives for Rh(III)-catalyzed annulations. 4- Trifluoroboratotetrahydroisoquinolones were generated under mild conditions, affording a regioisomerically complementary substitution pattern to other alkenes in related reactions. These new boron-containing building blocks were derivatized by N-arylations, retaining the boron substituent for further elaboration.