1427271-46-2Relevant academic research and scientific papers
Palladium-catalyzed 1,4-difunctionalization of butadiene to form skipped polyenes
McCammant, Matthew S.,Liao, Longyan,Sigman, Matthew S.
, p. 4167 - 4170 (2013)
A palladium-catalyzed 1,4-addition across the commodity chemical 1,3-butadiene to afford skipped polyene products is reported. Through a palladium σ → π → σ allyl isomerization, two new carbon-carbon bonds are formed with high regioselectivity and trans s
