14275-48-0Relevant articles and documents
Further evidence of SET mechanism during the LAH reduction of optically active 1-bromo 1-methyl 2,2-diphenyl cyclopropane.
Hatem, J.,Meslem, J. M.,Waegell, B.
, p. 3723 - 3724 (1986)
The stereochemical outcome of the reduction os 1(-) (R) with TBTH, SMEAH or LAH shows that with the latter a radical intermediate is involved.
Mechanism of Organocalcium Reagent Formation.
Walborsky, H. M.,Hamdouchi, C.
, p. 1187 - 1193 (1993)
The stereochemistry of the reaction of (S)-(+)-1-bromo- and (S)-(+)-1-chloro-1-methyl-2,2-diphenylcyclopropane and (S)-(+)-1-bromo-1-(methoxymethyl)-2,2-diphenylcyclopropane with calcium-aromatic complexes is reported as is its reaction with a radical clo
Reaction of a chiral cyclopropyl halide with alkali metals in alcohol solvents. The surface nature of the reaction
Walborsky,Ollman,Hamdouchi,Topolski
, p. 761 - 764 (2007/10/02)
An alcohol solution (methanol, isopropanol or t-butanol) of (S)-(+)-1-bromo-1-methyl-2,2-diphenylcyclopropane (1) was treated with an alkali metal (lithium, sodium, or potassium). The resultant hydrocarbon. (R)-(-)-1-methyl-2,2-diphenylcyclopropane (2), w
Electron transfer reactions from alkali metal surfaces to (+/-) and (S)-(-)-1,3-dimethoxy-1,1-diphenylbutane. Studies on 1,3-elimination
Walborsky, Harry M.,Murari, Martha Pass
, p. 2464 - 2470 (2007/10/02)
The 1,3-elimination of methoxide by carbanions generated from the reaction of (+/-)-1,3-dimethoxy-1,1-diphenylbutane with the alkali metals, lithium, sodium, and potassium, in various solvents was studied to determine the significance of cation-methoxyl c
