142867-82-1Relevant academic research and scientific papers
Enantioselective total synthesis of (-)-decarbamoylsaxitoxin
Hong, Chang Yong,Kishi, Yoshito
, p. 7001 - 7006 (1992)
An enantioselective total synthesis of (-)-decarbamoylsaxitoxin (2) has been accomplished, using the asymmetric trimolecular cyclization of 6, i.e., 6 + (R)-glyceraldehyde 2,3-acetonide + Si(NCS)4 → α-7, as the key step. The structure of the ma
