Journal of the American Chemical Society p. 7001 - 7006 (1992)
Update date:2022-08-04
Topics:
Hong, Chang Yong
Kishi, Yoshito
An enantioselective total synthesis of (-)-decarbamoylsaxitoxin (2) has been accomplished, using the asymmetric trimolecular cyclization of 6, i.e., 6 + (R)-glyceraldehyde 2,3-acetonide + Si(NCS)4 → α-7, as the key step. The structure of the ma
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