1428671-98-0

Basic information

• Product Name: (5S,6S,7R,9Z,11R)-11-{2-[bis(4-methoxyphenyl)(phenyl)methoxy]ethyl}-5-{2-[(3,4-dimethoxybenzyl)oxy]ethyl}-2,2,3,3,6,13,13,14,14-nonamethyl-4,12-dioxa-3,13-disilapentadec-9-en-7-ol
• CAS NO: 1428671-98-0
• Molecular Weight: 929.395
• Mol File: 1428671-98-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (5S,6S,7R,9Z,11R)-11-{2-[bis(4-methoxyphenyl)(phenyl)methoxy]ethyl}-5-{2-[(3,4-dimethoxybenzyl)oxy]ethyl}-2,2,3,3,6,13,13,14,14-nonamethyl-4,12-dioxa-3,13-disilapentadec-9-en-7-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (5S,6S,7R,9Z,11R)-11-{2-[bis(4-methoxyphenyl)(phenyl)methoxy]ethyl}-5-{2-[(3,4-dimethoxybenzyl)oxy]ethyl}-2,2,3,3,6,13,13,14,14-nonamethyl-4,12-dioxa-3,13-disilapentadec-9-en-7-ol(1428671-98-0)
• EPA Substance Registry System: (5S,6S,7R,9Z,11R)-11-{2-[bis(4-methoxyphenyl)(phenyl)methoxy]ethyl}-5-{2-[(3,4-dimethoxybenzyl)oxy]ethyl}-2,2,3,3,6,13,13,14,14-nonamethyl-4,12-dioxa-3,13-disilapentadec-9-en-7-ol(1428671-98-0)

Safety Data

• Hazardous Substances Data: 1428671-98-0(Hazardous Substances Data)

Upstream product

• 1428671-97-9 {[(1R,2S)-1-{2-[bis(4-methoxyphenyl)(phenyl)methoxy]ethyl}-2-(4,4,5,5-tetraphenyl-1,3,2-dioxaborolan-2-yl)but-3-en-1-yl]oxy}(tert-butyl)dimethylsilan 

Downstream Products

• 1428671-99-1 C₅₆H₈₆O₉Si₃ 
• 1428672-03-0 3,9-bis-O-[tert-butyl(dimethyl)silyl]-2,4,6,8,10-pentadeoxy-1-O-(3,4-dimethoxybenzyl)-4-methyl-5,7-O-(oxomethylene)-D-glycero-D-gluco-undecitol 
• 1428672-04-1 C₃₄H₆₀O₉Si₂ 
• 1428672-01-8 11-O-[bis(4-methoxyphenyl)(phenyl)methyl]-3,9-bis-O-[tert-butyl(dimethyl)silyl]-2,4,6,8,10-pentadeoxy-1-O-(3,4-dimethoxybenzyl)-4-methyl-D-glycero-D-gluco-undecitol 
• 1428672-02-9 11-O-[bis(4-methoxyphenyl)(phenyl)methyl]-3,9-bis-O-[tert-butyl(dimethyl)silyl]-2,4,6,8,10-pentadeoxy-1-O-(3,4-dimethoxybenzyl)-4-methyl-5,7-O-(oxomethylene)-D-glycero-D-gluco-undecitol 

Relevant articles and documents

Enantio- and diastereoselective synthesis of N-acetyl dihydrotetrafibricin methyl ester

A highly diastereoselective synthesis of N-acetyl dihydrotetrafibricin methyl ester (34) is described. The synthesis features three enantioselective double allylboration reactions and an intramolecular hydrosilylation/Fleming- Tamao oxidation sequence to establish seven of the hydroxy-bearing stereocenters of 34. Especially noteworthy is the fragment-assembly double allyboration reaction of 2 and 7 using reagent 3, which provides the advanced intermediate 6 with >20:1 diastereoselectivity.