14289-61-3Relevant articles and documents
Rhodium-Catalyzed Enantioselective Intermolecular Hydroalkoxylation of Allenes and Alkynes with Alcohols: Synthesis of Branched Allylic Ethers
Liu, Zi,Breit, Bernhard
supporting information, p. 8440 - 8443 (2016/07/19)
Regio- and enantioselective additions of alcohols to either terminal allenes or internal alkynes provides access to allylic ethers by using a RhI/diphenyl phosphate catalytic system. This method provides an atom-economic way to obtain chiral aliphatic and aryl allylic ethers in moderate to good yield with good to excellent enantioselectivities.
Organoselenium-catalyzed, hydroxy-controlled regio- and stereoselective amination of terminal alkenes: Efficient synthesis of 3-amino allylic alcohols
Deng, Zhimin,Wei, Jialiang,Liao, Lihao,Huang, Haiyan,Zhao, Xiaodan
supporting information, p. 1834 - 1837 (2015/04/27)
An efficient route to prepare 3-amino allylic alcohols in excellent regio- and stereoselectivity in the presence of bases by orangoselenium catalysis has been developed. In the absence of bases α,β-unsaturated aldehydes were formed in up to 97% yield. Control experiments reveal that the hydroxy group is crucial for the direct amination.
Synthesis of N-protected allylic amines from allyl ethers
Kim, Ji Duck,Lee, Min Hee,Han, Gyoonhee,Park, Hyunju,Zee, Ok Pyo,Jung, Young Hoon
, p. 8257 - 8266 (2007/10/03)
A synthetic method for N-protected allylic amines from allyl ethers using chlorosulfonyl isocyanate (CSI) is presented. The reaction of 4-phenylbut-2-enyl methyl ether (1i) with CSI afforded methyl N-(1-benzylallyl)carbamate (2i) and methyl N-(4-phenylbut
[2,3]-Wittig rearrangement initiated by 1,5-hydrogen atom transfer from an o-iodophenyl group on the α-carbon of allylic ethers by reduction with SmI2
Kunishima, Munetaka,Hioki, Kazuhito,Nakata, Daisuke,Nogawa, Shigenobu,Tani, Shohei
, p. 683 - 684 (2007/10/03)
Intramolecular 1,5-hydrogen atom transfer of an aryl radical generated by reduction of an o-iodophenyl group on the allylic position of allyl ethers by SmI2 regioselectively generates α-allyloxy carbanions, which undergo [2,3]-Wittig rearrangem