148761-93-7Relevant articles and documents
[2,3]-Wittig rearrangement initiated by 1,5-hydrogen atom transfer from an o-iodophenyl group on the α-carbon of allylic ethers by reduction with SmI2
Kunishima, Munetaka,Hioki, Kazuhito,Nakata, Daisuke,Nogawa, Shigenobu,Tani, Shohei
, p. 683 - 684 (1999)
Intramolecular 1,5-hydrogen atom transfer of an aryl radical generated by reduction of an o-iodophenyl group on the allylic position of allyl ethers by SmI2 regioselectively generates α-allyloxy carbanions, which undergo [2,3]-Wittig rearrangem
Regio- and enantioselective synthesis of chiral pyrimidine acyclic nucleosides via rhodium-catalyzed asymmetric allylation of pyrimidines
Liang, Lei,Xie, Ming-Sheng,Qin, Tao,Zhu, Man,Qu, Gui-Rong,Guo, Ha-Ming
supporting information, p. 5212 - 5215 (2017/11/06)
A direct route to branched N-allylpyrimidine analogues is herein reported via the highly regio- and enantioselective asymmetric allylation of pyrimidines with racemic allylic carbonates. With [Rh(COD)Cl]2/chiral diphosphine as the catalyst, a r