1429470-05-2

Upstream product

• 50-00-0 formaldehyd 
• 101906-25-6 (2R)-benzyl-(2-methylpent-4-ynyl) ether 
• 86951-92-0 (2S)-3-Benzyloxy-2-methyl-1-p-(toluenesulphonyloxy)propane 
• 63930-49-4 (R)-3-(benzyloxy)-2-methylpropan-1-ol 

Downstream Products

• 1429470-11-0 (2R,4R,5S)-6-(tert-butyldiphenylsilyloxy)-4-(methoxymethoxy)-2,5-dimethylhexan-1-ol 
• 1429470-04-1 (5R,6S)-6,10,10-trimethyl-5-((2R)-2-methylbut-3-enyl)-9,9-diphenyl-2,4,8-trioxa-9-silaundecane 
• 1429470-12-1 3-((4S,5S)-5-((3R,5R,6S,E)-7-(tert-butyldiphenylsilyloxy)-5-(methoxymethoxy)-3,6-dimethylhept-1-enyl)-2,2-dimethyl-1,3-dioxolan-4-yl)propan-1-ol 
• 1429470-13-2 C₃₅H₅₆O₆Si 
• 1429470-14-3 (5R,6S)-5-((2S)-4-((4S,5S)-5-(but-3-enyl)-2,2-dimethyl-1,3-dioxolan-4-yl)-2-methylbutyl)-6,10,10-trimethyl-9,9-diphenyl-2,4,8-trioxa-9-silaundecane 
• 1429470-07-4 ((2R,3R)-3-((2R)-3-(benzyloxy)-2-methylpropyl)oxiran-2-yl)methanol 
• 1429470-08-5 (2S,3R,5R)-6-(benzyloxy)-2,5-dimethylhexan-1,3-diol 
• 1429470-09-6 C₃₁H₄₂O₃Si 
• 1429470-10-9 C₃₃H₄₆O₄Si 

Relevant academic research and scientific papers

Toward the synthesis of tulearin C: Stereoselective synthesis of the C1-C18 macrolactone core

The asymmetric and convergent synthesis of fully functionalized macrocyclic core of tulearin C is described. Sharpless asymmetric epoxidation, Gillman's reaction, olefin cross metathesis, α aminoxylation, and ring closing metathesis reactions are the key