142967-67-7

Basic information

• Product Name: Methyl 3-O-allyl-2,4-di-O-benzyl-6-deoxy-6-iodo-α-D-glucopyranoside
• Synonyms: Methyl 3-O-allyl-2,4-di-O-benzyl-6-deoxy-6-iodo-α-D-glucopyranoside
• CAS NO: 142967-67-7
• Molecular Weight: 524.396
• Mol File: 142967-67-7.mol

Chemical Properties

• CAS DataBase Reference: Methyl 3-O-allyl-2,4-di-O-benzyl-6-deoxy-6-iodo-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl 3-O-allyl-2,4-di-O-benzyl-6-deoxy-6-iodo-α-D-glucopyranoside(142967-67-7)
• EPA Substance Registry System: Methyl 3-O-allyl-2,4-di-O-benzyl-6-deoxy-6-iodo-α-D-glucopyranoside(142967-67-7)

Safety Data

• Hazardous Substances Data: 142967-67-7(Hazardous Substances Data)

Upstream product

• 58341-56-3 Methyl 3-O-allyl-2-O-benzyl-4,6-O-benzylidene-α-D-glucopyranoside 
• 15038-71-8 methyl 2-O-benzyl-4,6-O-benzylidene-α-D-glucopyranoside 
• 58341-60-9 Methyl 3-O-allyl-2,4-di-O-benzyl-α-D-glucopyranoside 

Downstream Products

• 114283-90-8 1,3-Di-O-acetyl-2,4-di-O-benzyl-6-deoxy-α,β-D-glucopyranose 
• 127874-91-3 3-O-allyl-2,4-di-O-benzyl-6-deoxy-α/β-D-glucopyranose 
• 42822-31-1 2,4-Di-O-benzyl-6-deoxy-α,β-D-glucopyranose 
• 141942-25-8 1,3-Anhydro-2,4-di-O-benzyl-β-D-glucopyranose 
• 134311-58-3 3-O-Acetyl-2,4-di-O-benzyl-6-deoxy-α-D-glucopyranosyl chloride 
• 134311-55-0 Methyl 3-O-allyl-2,4-di-O-benzyl-6-deoxy-α-D-glucopyranoside 

Relevant articles and documents

Synthesis and conformational analysis of substituted 2,6-dioxabicycloheptanes: 1,3-anhydro-2,4-di-O-benzyl-6-deoxy-β-D-glucopyranose by 1H-NMR spectroscopy and molecular mechanics calculation

A highly selective ring opening reduction of methyl 3-O-allyl-2-O-benzyl-4,6-O-benzylidene-α-D-glucopyranoside provided the 2,4-di-O-benzyl derivative.This was toluenesulfonylated or iodinated and subsequently reduced to give crystalline methyl 3-O-allyl-