127874-91-3

Upstream product

• 134311-55-0 Methyl 3-O-allyl-2,4-di-O-benzyl-6-deoxy-α-D-glucopyranoside 
• 114219-31-7 (2S,3R,4S,5S,6R)-3,5-Bis-benzyloxy-2-methoxy-6-methyl-tetrahydro-pyran-4-ol 
• 106-95-6 allyl bromide 
• 114219-30-6 methyl 2,4-di-O-benzyl-6-O-tosyl-α-D-glucopyranoside 
• 142967-66-6 Methyl 3-O-allyl-2,4-di-O-benzyl-6-O-p-tolylsulfonyl-α-D-glucopyranoside 
• 142967-65-5 Methyl 3-O-allyl-2-O-benzyl-6-O-p-tolylsulfonyl-α-D-glucopyranoside 
• 58341-56-3 Methyl 3-O-allyl-2-O-benzyl-4,6-O-benzylidene-α-D-glucopyranoside 
• 142967-67-7 Methyl 3-O-allyl-2,4-di-O-benzyl-6-deoxy-6-iodo-α-D-glucopyranoside 
• 58341-60-9 Methyl 3-O-allyl-2,4-di-O-benzyl-α-D-glucopyranoside 
• 58341-57-4 Methyl 3-O-allyl-2-O-benzyl-α-D-glucopyranoside 
• 15038-71-8 methyl 2-O-benzyl-4,6-O-benzylidene-α-D-glucopyranoside 
• 6619-09-6 methyl 6-O-tosyl-α-D-glucopyranoside 
• 100-39-0 benzyl bromide 
• 58341-67-6 methyl 2,4-di-O-benzyl-α-D-glucopyranoside 

Downstream Products

• 42822-31-1 2,4-Di-O-benzyl-6-deoxy-α,β-D-glucopyranose 
• 134311-58-3 3-O-Acetyl-2,4-di-O-benzyl-6-deoxy-α-D-glucopyranosyl chloride 
• 141942-25-8 1,3-Anhydro-2,4-di-O-benzyl-β-D-glucopyranose 
• 114283-90-8 1,3-Di-O-acetyl-2,4-di-O-benzyl-6-deoxy-α,β-D-glucopyranose 

Relevant academic research and scientific papers

Synthesis and conformational analysis of substituted 2,6-dioxabicycloheptanes: 1,3-anhydro-2,4-di-O-benzyl-6-deoxy-β-D-glucopyranose by 1H-NMR spectroscopy and molecular mechanics calculation

A highly selective ring opening reduction of methyl 3-O-allyl-2-O-benzyl-4,6-O-benzylidene-α-D-glucopyranoside provided the 2,4-di-O-benzyl derivative.This was toluenesulfonylated or iodinated and subsequently reduced to give crystalline methyl 3-O-allyl-

Partially Benzylated Derivatives of 6-Deoxy-D-glucose

Several partially benzylated derivatives of 6-deoxy-D-glucose (D-quinovose) were synthesized from appropriate di-O-benzyl-D-glucosides whose primary hydroxyl group is unprotected, via unimolar tosylation and subsequent reduction with LiAlH4.