142981-58-6

Basic information

• Product Name: decanoylphenyldimethylsilane tosylhydrazone
• Synonyms: decanoylphenyldimethylsilane tosylhydrazone
• CAS NO: 142981-58-6
• Molecular Weight: 458.74
• Mol File: 142981-58-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: decanoylphenyldimethylsilane tosylhydrazone(CAS DataBase Reference)
• NIST Chemistry Reference: decanoylphenyldimethylsilane tosylhydrazone(142981-58-6)
• EPA Substance Registry System: decanoylphenyldimethylsilane tosylhydrazone(142981-58-6)

Safety Data

• Hazardous Substances Data: 142981-58-6(Hazardous Substances Data)

Upstream product

• 125828-13-9 decanoyldimethyl(phenyl)silane 
• 1576-35-8 toluene-4-sulfonic acid hydrazide 

Downstream Products

• 1975-78-6 n-decanenitrile 
• 110-42-9 Methyl decanoate 

Relevant articles and documents

Electrochemical Oxidation of Acylsilanes and Their Tosylhydrazones

Oxidation potentials of acylsilanes were found to be much less positive than those of ketones and aldehydes.The effect of silicon is attributed to the rise of the HOMO level by the interaction between the C-Si ? orbital and the nonbonding p orbital of the carbonyl oxygen which in turn favors the electron transfer.Preparative electrochemical oxidation of acylsilanes proceeded smoothly, giving rise to facile cleavage of the C-Si bond and the introduction of nucleophiles such as alcohols, water, and carbamates onto the carbonyl carbon.Electrochemical properties of tosylhydrazones of acylsilanes were also investigated.A decrease in oxidation potential of tosylhydrazones caused by silyl substitution was found to be smaller than that for carbonyl compounds.Preparative electrochemical oxidation of tosylhydrazones of acylsilanes gave the corresponding nitriles with consumption of a catalytic amount of electricity.