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110-42-9

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110-42-9 Usage

Chemical Properties

Clear colorless liquid

Uses

Different sources of media describe the Uses of 110-42-9 differently. You can refer to the following data:
1. Intermediate for detergents, emulsifiers, wetting agents, stabilizers, resins, lubricants, plasticizers.
2. It is employed as an intermediate for caproic acid, detergents, emulsifiers, wetting agents, stabilizers, resins, lubricants, plasticizers and flavoring. As a chemical intermediate for alkanolamides, fatty alcohols & acids.

Synthesis Reference(s)

The Journal of Organic Chemistry, 46, p. 3936, 1981 DOI: 10.1021/jo00332a045Synthesis, p. 899, 1981 DOI: 10.1055/s-1981-29640

General Description

Methyl decanoate is reported to occur in parmesan cheese, sparkling wine and banana.

Flammability and Explosibility

Nonflammable

Purification Methods

Pass the ester through alumina before use and distil in a vacuum. [Beilstein 2 IV 1044.]

Check Digit Verification of cas no

The CAS Registry Mumber 110-42-9 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 1,1 and 0 respectively; the second part has 2 digits, 4 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 110-42:
(5*1)+(4*1)+(3*0)+(2*4)+(1*2)=19
19 % 10 = 9
So 110-42-9 is a valid CAS Registry Number.
InChI:InChI=1/C11H22O2/c1-3-4-5-6-7-8-9-10-11(12)13-2/h3-10H2,1-2H3

110-42-9 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
  • Price
  • Detail
  • Alfa Aesar

  • (A15658)  Methyl decanoate, 99%   

  • 110-42-9

  • 50g

  • 417.0CNY

  • Detail
  • Alfa Aesar

  • (A15658)  Methyl decanoate, 99%   

  • 110-42-9

  • 100g

  • 448.0CNY

  • Detail
  • Alfa Aesar

  • (A15658)  Methyl decanoate, 99%   

  • 110-42-9

  • 250g

  • 991.0CNY

  • Detail
  • USP

  • (1424233)  Methylcaprate  United States Pharmacopeia (USP) Reference Standard

  • 110-42-9

  • 1424233-300MG

  • 4,588.74CNY

  • Detail
  • Sigma-Aldrich

  • (21479)  Methyldecanoate  analytical standard

  • 110-42-9

  • 21479-1ML

  • 490.23CNY

  • Detail
  • Sigma-Aldrich

  • (21479)  Methyldecanoate  analytical standard

  • 110-42-9

  • 21479-5ML

  • 2,183.22CNY

  • Detail

110-42-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name METHYL DECANOATE

1.2 Other means of identification

Product number -
Other names methyl n-caprate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Food additives -> Flavoring Agents
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:110-42-9 SDS

110-42-9Synthetic route

methanol
67-56-1

methanol

1-decanoic acid
334-48-5

1-decanoic acid

Methyl decanoate
110-42-9

Methyl decanoate

Conditions
ConditionsYield
With tetrachloromethane at 20℃; for 12h; UV-irradiation;99%
With Mesoscopically Assembled SulfatedZirconia Nanoparticles at 49.84℃; for 8h; Catalytic behavior; Reagent/catalyst; Temperature;97%
With sulfuric acid; acetonitrile at 80 - 85℃; for 16 - 18h;97%
2-n-nonyl-1,3-dioxolane
4353-06-4

2-n-nonyl-1,3-dioxolane

methanol
67-56-1

methanol

Methyl decanoate
110-42-9

Methyl decanoate

Conditions
ConditionsYield
With hydrogenchloride; dihydrogen peroxide98%
Dimethoxymethane
109-87-5

Dimethoxymethane

n-decanoyl chloride
112-13-0

n-decanoyl chloride

A

Methyl decanoate
110-42-9

Methyl decanoate

B

chloromethyl methyl ether
107-30-2

chloromethyl methyl ether

Conditions
ConditionsYield
sulfuric acid at 55 - 60℃; for 2h; exchange reaction;A n/a
B 97%
tert-butyl methyl ether
1634-04-4

tert-butyl methyl ether

1-decanoic acid
334-48-5

1-decanoic acid

Methyl decanoate
110-42-9

Methyl decanoate

Conditions
ConditionsYield
With sulfuric acid Reflux; regioselective reaction;97%
methanol
67-56-1

methanol

1,1-dimethoxy decane
7779-41-1

1,1-dimethoxy decane

Methyl decanoate
110-42-9

Methyl decanoate

Conditions
ConditionsYield
With hydrogenchloride; dihydrogen peroxide 1.) <20 deg C, 30 min; 2.) 40 deg C, 3 h;96%
1-tert-Butylperoxy-1-methoxy-decane
104383-13-3

1-tert-Butylperoxy-1-methoxy-decane

Methyl decanoate
110-42-9

Methyl decanoate

Conditions
ConditionsYield
In methanol at 60℃;94%
Decanoic acid, tert-butyldimethylsilyl ester

Decanoic acid, tert-butyldimethylsilyl ester

methanol
67-56-1

methanol

Methyl decanoate
110-42-9

Methyl decanoate

Conditions
ConditionsYield
Stage #1: Decanoic acid, tert-butyldimethylsilyl ester; methanol; carbon tetrabromide at 20℃; for 0.5h; Irradiation;
Stage #2: at 20℃; for 3h;
92%
methanol
67-56-1

methanol

1-Decanol
112-30-1

1-Decanol

Methyl decanoate
110-42-9

Methyl decanoate

Conditions
ConditionsYield
With [bis(acetoxy)iodo]benzene; iodine at 20℃; for 4h;91%
With pyridine; tert-butylhypochlorite In dichloromethane for 1h;99 % Chromat.
With (2-hydroxyethyl)(methyl)amine; bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]; caesium carbonate In acetone at 25℃; for 24h; Inert atmosphere;82 %Chromat.
methanol
67-56-1

methanol

caprinaldehyde
112-31-2

caprinaldehyde

Methyl decanoate
110-42-9

Methyl decanoate

Conditions
ConditionsYield
With hydrogenchloride; dihydrogen peroxide90%
With potassium bromide for 1.8h; Ambient temperature; anode, platinum plate; cathode, carbon rod;85%
With ammonium cerium (IV) nitrate; lithium bromide In neat liquid at 35 - 40℃; for 3.5h;74%
methanol
67-56-1

methanol

capric acid triglyceride
621-71-6

capric acid triglyceride

A

Methyl decanoate
110-42-9

Methyl decanoate

B

glycerol
56-81-5

glycerol

Conditions
ConditionsYield
bis(trimethylsilyl)sulphate In dichloromethane; 1,2-dichloro-ethane for 8.5h; Heating;A 89%
B 82%
C19H40O2Si
866096-42-6

C19H40O2Si

methanol
67-56-1

methanol

Methyl decanoate
110-42-9

Methyl decanoate

Conditions
ConditionsYield
Stage #1: C19H40O2Si; methanol; carbon tetrabromide at 20℃; for 0.5h; Irradiation;
Stage #2: at 20℃; for 8h;
89%
methanol
67-56-1

methanol

caprinaldehyde
112-31-2

caprinaldehyde

A

1-decanoic acid
334-48-5

1-decanoic acid

B

Methyl decanoate
110-42-9

Methyl decanoate

Conditions
ConditionsYield
With dipyridinium dichromate In N,N-dimethyl-formamide for 20h; Ambient temperature;A n/a
B 87%
methanol
67-56-1

methanol

decanoyltriphenylsilane
143006-23-9

decanoyltriphenylsilane

Methyl decanoate
110-42-9

Methyl decanoate

Conditions
ConditionsYield
With tetraethylammonium tosylate Ambient temperature; electrolysis;87%
methanol
67-56-1

methanol

decanoic acid ethyl ester
110-38-3

decanoic acid ethyl ester

Methyl decanoate
110-42-9

Methyl decanoate

Conditions
ConditionsYield
With (N3/phenyl-/(diethylamino)methyl-triazolyl)-modified DMOF [DMOF= Zn2(2-amino-terephthalate)2(dabco)] at 130℃; for 20h;84%
With di(n-butyl)tin oxide In methanol for 12h; Heating;80%
With lanthanum complex grafted upon hydrotalcite for 8h; pH=10; Reflux;56%
With nitrogen-functionalized metal-organic framework catalyst at 180℃; for 24h; Inert atmosphere;
1-methoxydecane
7289-52-3

1-methoxydecane

A

Methyl decanoate
110-42-9

Methyl decanoate

B

n-decyl methanoate
5451-52-5

n-decyl methanoate

Conditions
ConditionsYield
With sodium periodate; ruthenium trichloride In tetrachloromethane; water; acetonitrile for 8h; Ambient temperature;A 83%
B n/a
C26H38O2Si

C26H38O2Si

methanol
67-56-1

methanol

Methyl decanoate
110-42-9

Methyl decanoate

Conditions
ConditionsYield
Stage #1: C26H38O2Si; methanol; carbon tetrabromide at 20℃; for 0.5h; Irradiation;
Stage #2: at 20℃; for 9h;
81%
methanol
67-56-1

methanol

1-(Methyl-diphenyl-silanyl)-decan-1-one
142981-56-4

1-(Methyl-diphenyl-silanyl)-decan-1-one

Methyl decanoate
110-42-9

Methyl decanoate

Conditions
ConditionsYield
With tetraethylammonium tosylate Ambient temperature; electrolysis;77%
methanol
67-56-1

methanol

decanoyldimethyl(phenyl)silane
125828-13-9

decanoyldimethyl(phenyl)silane

Methyl decanoate
110-42-9

Methyl decanoate

Conditions
ConditionsYield
With tetraethylammonium tosylate Ambient temperature; electrolysis;76%
1,1-dimethoxy decane
7779-41-1

1,1-dimethoxy decane

A

2-bromo-1,1-dimethoxydecane
18207-21-1

2-bromo-1,1-dimethoxydecane

B

Methyl decanoate
110-42-9

Methyl decanoate

Conditions
ConditionsYield
With methanol; tetrabutylammomium bromide; bromine In dichloromethane for 0.5h; Yields of byproduct given;A 69%
B n/a
With methanol; tetrabutylammomium bromide; bromine In dichloromethane for 0.5h; Yield given;A 69%
B n/a
C22H38O4
14202-22-3

C22H38O4

A

Methyl decanoate
110-42-9

Methyl decanoate

B

dimethyl 1,18-octadecanedioate
1472-93-1

dimethyl 1,18-octadecanedioate

C

(R)-6-hexyl-tetrahydro-2H-pyran-2-one
108861-12-7

(R)-6-hexyl-tetrahydro-2H-pyran-2-one

Conditions
ConditionsYield
Stage #1: C22H38O4
Stage #2: With hydrogen at 75℃; under 7500.75 Torr; for 14h; regioselective reaction;
A n/a
B n/a
C 66%
acetic acid methyl ester
79-20-9

acetic acid methyl ester

nonyl alcohol
143-08-8

nonyl alcohol

Methyl decanoate
110-42-9

Methyl decanoate

Conditions
ConditionsYield
With C15H17ClIrNOP; potassium tert-butylate In neat (no solvent) at 60℃; for 12h; Schlenk technique; Inert atmosphere; Glovebox;59%
methanol
67-56-1

methanol

n-butyl decanoate
30673-36-0

n-butyl decanoate

Methyl decanoate
110-42-9

Methyl decanoate

Conditions
ConditionsYield
With lanthanum complex grafted upon hydrotalcite for 8h; pH=10; Catalytic behavior; Time; Reagent/catalyst; Concentration; pH-value; Reflux;55%
methyl 9-decenoate
25601-41-6

methyl 9-decenoate

carbon monoxide
201230-82-2

carbon monoxide

A

Methyl decanoate
110-42-9

Methyl decanoate

B

methyl 11-oxoundecanoate
1931-65-3

methyl 11-oxoundecanoate

C

methyl 9-methyl-10-oxodecanoate
171076-49-6

methyl 9-methyl-10-oxodecanoate

D

methyl 8-formyldecanoate

methyl 8-formyldecanoate

Conditions
ConditionsYield
With dicarbonylacetylacetonato rhodium (I); hydrogen; triphenylphosphine at 60℃; under 30003 Torr; for 12h; Temperature; Pressure; Reagent/catalyst;A 6%
B 55%
C 28%
D 11%
methanol
67-56-1

methanol

caprinaldehyde
112-31-2

caprinaldehyde

A

Methyl decanoate
110-42-9

Methyl decanoate

B

methyl ester of α-bromodecanoic acid
7357-56-4

methyl ester of α-bromodecanoic acid

Conditions
ConditionsYield
Stage #1: caprinaldehyde With ammonium cerium (IV) nitrate; lithium bromide In neat liquid
Stage #2: methanol In neat liquid at 35 - 40℃; for 3.5h;
A 29 %Chromat.
B 53%
decanoylphenyldimethylsilane tosylhydrazone
142981-58-6

decanoylphenyldimethylsilane tosylhydrazone

A

n-decanenitrile
1975-78-6

n-decanenitrile

B

Methyl decanoate
110-42-9

Methyl decanoate

Conditions
ConditionsYield
With tetrabutylammonium tetrafluoroborate In methanol; dichloromethane electrolysis;A 45%
B 11%
methanol
67-56-1

methanol

capric anhydride
2082-76-0

capric anhydride

[hydroxy(tosyloxy)iodo]benzene
27126-76-7

[hydroxy(tosyloxy)iodo]benzene

A

iodobenzene
591-50-4

iodobenzene

B

Methyl decanoate
110-42-9

Methyl decanoate

C

methyl 2-tosyloxydecanoate

methyl 2-tosyloxydecanoate

Conditions
ConditionsYield
Stage #1: capric anhydride; [hydroxy(tosyloxy)iodo]benzene at 100℃; for 0.333333h;
Stage #2: methanol With toluene-4-sulfonic acid for 4h; Heating;
A n/a
B n/a
C 41%
methanol
67-56-1

methanol

δ-furfurylidenelevulinic acid methyl ester

δ-furfurylidenelevulinic acid methyl ester

A

1-decanoic acid
334-48-5

1-decanoic acid

B

Methyl decanoate
110-42-9

Methyl decanoate

Conditions
ConditionsYield
With palladium 10% on activated carbon; W(OTf)6; hydrogen at 180℃; under 15001.5 Torr; for 8h; Autoclave;A 2.7%
B 15.3%
adipic acid monomethyl ester
627-91-8

adipic acid monomethyl ester

hexanoic acid
142-62-1

hexanoic acid

Methyl decanoate
110-42-9

Methyl decanoate

Conditions
ConditionsYield
With methanol; sodium Electrolysis.an Platin-Elektroden;
1-decanoic acid
334-48-5

1-decanoic acid

Methyl decanoate
110-42-9

Methyl decanoate

Conditions
ConditionsYield
for 0.5h;
methyl 8-hydroxyoctadecanoate
2379-98-8

methyl 8-hydroxyoctadecanoate

A

Methyl decanoate
110-42-9

Methyl decanoate

B

methyl undecanoate
1731-86-8

methyl undecanoate

C

dimethyl 1,7-heptanedioate
1732-08-7

dimethyl 1,7-heptanedioate

D

dimethyl subarate
1732-09-8

dimethyl subarate

Conditions
ConditionsYield
With potassium permanganate In acetic acid Product distribution; oxidative degradation and methylation;
Methyl decanoate
110-42-9

Methyl decanoate

1-Decanol
112-30-1

1-Decanol

Conditions
ConditionsYield
With hydrogen In hexane at 200℃; under 15001.5 Torr; for 8h; Reagent/catalyst;99.8%
Stage #1: Methyl decanoate With diethylzinc; lithium chloride In tetrahydrofuran; hexane at 20℃; for 6h; Inert atmosphere;
Stage #2: With sodium hydroxide In tetrahydrofuran; hexane; water at 20℃; for 8h; Inert atmosphere; chemoselective reaction;
98%
With samarium diiodide; water; triethylamine In tetrahydrofuran at 20℃; for 15h; Inert atmosphere;95%
monoethyl ether of triethylene glycol
112-50-5

monoethyl ether of triethylene glycol

Methyl decanoate
110-42-9

Methyl decanoate

1-Decanol
112-30-1

1-Decanol

Conditions
ConditionsYield
With sodium borohydrid In 5,5-dimethyl-1,3-cyclohexadiene99%
Methyl decanoate
110-42-9

Methyl decanoate

A

methanol
67-56-1

methanol

B

1-Decanol
112-30-1

1-Decanol

Conditions
ConditionsYield
With C66H102N4OP2Ru; hydrogen In toluene at 105℃; under 22502.3 Torr; for 20h; Inert atmosphere; Glovebox;A n/a
B 99%
With C30H37ClN4ORu; hydrogen; sodium t-butanolate In toluene at 105℃; under 22502.3 Torr; for 20h; Glovebox; Sealed tube; Overall yield = >99 %;
Methyl decanoate
110-42-9

Methyl decanoate

acetophenone
98-86-2

acetophenone

decanoyl benzoyl methane
87202-38-8

decanoyl benzoyl methane

Conditions
ConditionsYield
With sodium methylate In 5,5-dimethyl-1,3-cyclohexadiene for 1.25h; Claisen Condensation; Inert atmosphere; Reflux; Microwave irradiation;98.3%
Methyl decanoate
110-42-9

Methyl decanoate

ethylmagnesium bromide
925-90-6

ethylmagnesium bromide

1-nonyl-1-cyclopropanol
127460-69-9

1-nonyl-1-cyclopropanol

Conditions
ConditionsYield
With titanium(IV) isopropylate In diethyl ether at -78 - 0℃; for 0.5h;98%
With titanium(IV) isopropylate In diethyl ether at 18 - 20℃;97%
titanium(IV) isopropylate In diethyl ether at 18 - 20℃;95%
Diethylene glycol monobutyl ether
112-34-5

Diethylene glycol monobutyl ether

Methyl decanoate
110-42-9

Methyl decanoate

1-Decanol
112-30-1

1-Decanol

Conditions
ConditionsYield
With sodium borohydrid In 5,5-dimethyl-1,3-cyclohexadiene98%
Methyl decanoate
110-42-9

Methyl decanoate

n-[1,1-2H2]decanol
42006-99-5

n-[1,1-2H2]decanol

Conditions
ConditionsYield
With lithium aluminium deuteride In tetrahydrofuran at -78℃; Reflux;98%
ethoxyethoxyethanol
111-90-0

ethoxyethoxyethanol

Methyl decanoate
110-42-9

Methyl decanoate

1-Decanol
112-30-1

1-Decanol

Conditions
ConditionsYield
With sodium borohydrid In 5,5-dimethyl-1,3-cyclohexadiene97%
Methyl decanoate
110-42-9

Methyl decanoate

benzyl alcohol
100-51-6

benzyl alcohol

benzyl decanoate
42175-41-7

benzyl decanoate

Conditions
ConditionsYield
With 1,3-bis(3,5-bis(trifluoro-ethyl)phenyl)thiourea; 4-pyrrolidin-1-ylpyridine In n-heptane for 24h; Reflux;96%
Methyl decanoate
110-42-9

Methyl decanoate

phenyl trifluoromethylsulfide
456-56-4

phenyl trifluoromethylsulfide

1,1,1-trifluoro-2-undecanone
26902-70-5

1,1,1-trifluoro-2-undecanone

Conditions
ConditionsYield
With Triethylgermyl-natrium In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide at -60℃; for 1.5h;95%
triethylsilane
617-86-7

triethylsilane

Methyl decanoate
110-42-9

Methyl decanoate

C17H38O2Si

C17H38O2Si

Conditions
ConditionsYield
With decacarbonyldirhenium(0) In toluene at 30℃; for 9h; Inert atmosphere; UV-irradiation; Schlenk technique;93%
Methyl decanoate
110-42-9

Methyl decanoate

[(1-methoxy-2-methyl-1-butenyl)oxy]trimethylsilane
123820-43-9, 123820-44-0, 84393-12-4

[(1-methoxy-2-methyl-1-butenyl)oxy]trimethylsilane

A

methyl 2-ethyl-2-methyl-3-oxododecanoate

methyl 2-ethyl-2-methyl-3-oxododecanoate

B

methyl 2-ethyl-2-methyl-3-(trimethylsiloxy)dodec-3-enoate

methyl 2-ethyl-2-methyl-3-(trimethylsiloxy)dodec-3-enoate

Conditions
ConditionsYield
With sodium hydroxide In N,N-dimethyl-formamide at 20 - 25℃; for 1h; Claisen condensation; Inert atmosphere;A 8%
B 90%
With sodium hydroxide In N,N-dimethyl-formamide at 15 - 20℃; for 1h; crossed Claisen condensation;
2-ethoxy-ethanol
110-80-5

2-ethoxy-ethanol

Methyl decanoate
110-42-9

Methyl decanoate

1-Decanol
112-30-1

1-Decanol

Conditions
ConditionsYield
With sodium borohydrid In 5,5-dimethyl-1,3-cyclohexadiene90%
tetrathioorthocarbonic acid tetramethyl ester
6156-25-8

tetrathioorthocarbonic acid tetramethyl ester

Methyl decanoate
110-42-9

Methyl decanoate

1,1-Bis-methylsulfanyl-undecan-2-one

1,1-Bis-methylsulfanyl-undecan-2-one

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran; hexane 1.) -95 deg C, 2 h, 2.) -78 deg C, 30 min;89%
2-(tert-butyldimethylsilyloxy)-1-methoxy-1-trimethylsilyloxy-1-propene
940867-32-3

2-(tert-butyldimethylsilyloxy)-1-methoxy-1-trimethylsilyloxy-1-propene

Methyl decanoate
110-42-9

Methyl decanoate

methyl 2-hydroxy-2-methyl-3-oxododecanoate

methyl 2-hydroxy-2-methyl-3-oxododecanoate

Conditions
ConditionsYield
Stage #1: 2-(tert-butyldimethylsilyloxy)-1-methoxy-1-trimethylsilyloxy-1-propene; Methyl decanoate With sodium hydroxide In 1-methyl-pyrrolidin-2-one at 20 - 25℃; for 3h; Claisen condensation; Inert atmosphere;
Stage #2: With tetrabutyl ammonium fluoride In tetrahydrofuran at 0 - 5℃; for 1h; Inert atmosphere;
89%
Methyl decanoate
110-42-9

Methyl decanoate

dimethyl(phenyl)silyllithium
3839-31-4

dimethyl(phenyl)silyllithium

1,1-bisdecan-1-ol
155397-14-1

1,1-bisdecan-1-ol

Conditions
ConditionsYield
In tetrahydrofuran at -78℃; for 3h;88%
tris(methylthio)methane
5418-86-0

tris(methylthio)methane

Methyl decanoate
110-42-9

Methyl decanoate

A

tetrathioorthocarbonic acid tetramethyl ester
6156-25-8

tetrathioorthocarbonic acid tetramethyl ester

B

1,1-Bis-methylsulfanyl-undecan-2-one

1,1-Bis-methylsulfanyl-undecan-2-one

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran; hexane 1.) -95 deg C, 2 h, 2.) -78 deg C, 30 min;A n/a
B 88%
1-methyl-1H-benzo[d][1,2,3]triazole
13351-73-0

1-methyl-1H-benzo[d][1,2,3]triazole

Methyl decanoate
110-42-9

Methyl decanoate

1-Benzotriazol-1-yl-undecan-2-one
189343-46-2

1-Benzotriazol-1-yl-undecan-2-one

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran; hexane at -78 - 20℃; for 12h;88%
Methyl decanoate
110-42-9

Methyl decanoate

dimethyl 1-(1-diazo-2-oxopropyl)phosphonate
90965-06-3

dimethyl 1-(1-diazo-2-oxopropyl)phosphonate

1-undecyne
2243-98-3

1-undecyne

Conditions
ConditionsYield
Stage #1: Methyl decanoate With diisobutylaluminium hydride In n-heptane; dichloromethane at -78℃;
Stage #2: dimethyl 1-(1-diazo-2-oxopropyl)phosphonate With potassium carbonate In methanol; n-heptane; dichloromethane at 20℃; Further stages.;
88%

110-42-9Related news

A shock tube study of METHYL DECANOATE (cas 110-42-9) autoignition at elevated pressures08/29/2019

A shock tube study of the autoignition of methyl decanoate, a candidate surrogate for biodiesel fuels containing large methyl esters, has been carried out. Ignition delay times were measured in reflected-shock-heated gases by monitoring electronically-excited OH chemiluminescence and pressure. M...detailed

A comprehensive study of METHYL DECANOATE (cas 110-42-9) pyrolysis08/28/2019

The thermal decomposition of methyl decanoate (MD) was studied in a bench-scale pyrolysis set-up equipped with a dedicated on-line analysis section including a GC × GC-FID/(TOF-MS). This analysis section enables quantitative and qualitative on-line analyses of the entire reactor effluent with h...detailed

A kinetic model for METHYL DECANOATE (cas 110-42-9) combustion08/27/2019

A detailed kinetic model for the oxidation of the biodiesel surrogate, methyl decanoate, has been developed and tested against a broad range of experimental data. The methyl decanoate model consists of both low and high temperature oxidation chemistry. It has been constructed strictly through th...detailed

Experimental and kinetic modeling investigation on METHYL DECANOATE (cas 110-42-9) pyrolysis at low and atmospheric pressures08/25/2019

The pyrolysis of methyl decanoate (MD), an ideal surrogate of biodiesels, was investigated in a flow reactor at the pressures of 30 and 760 Torr and the temperature ranging from 773 to 1198 K. A great variety of pyrolysis products including free radicals, n-alkanes, 1-alkenes, alkynes, unsaturat...detailed

Temperature and pressure dependence of densities and viscosities for binary mixtures of METHYL DECANOATE (cas 110-42-9) plus n-heptane08/22/2019

New experimental densities and viscosities data for binary mixtures of methyl decanoate plus n-heptane were reported at temperatures of (298.15, 308.15 and 318.15) K and pressures of (0.1–15) MPa. The expanded uncertainty for density measurement is estimated to be 2 kg m−3 and the relative expa...detailed

Full Length ArticleObtaining a reduced kinetic mechanism for METHYL DECANOATE (cas 110-42-9) using layerless neural networks08/20/2019

Major efforts in the search for techniques for the development of reduced kinetic mechanisms for biodiesel have been observed, since these mechanisms may have thousands of species. This paper proposes a reduction strategy and presents the development of a reduced kinetic mechanism for piloted je...detailed

110-42-9Relevant articles and documents

Development of mesoscopically assembled sulfated zirconia nanoparticles as promising heterogeneous and recyclable biodiesel catalysts

Das, Swapan K.,El-Safty, Sherif A.

, p. 3050 - 3059 (2013)

The nanoassembly of nearly monodisperse nanoparticles (NPs) as uniform building blocks to engineer zirconia (ZrO2) nanostructures with mesoscopic ordering by using a template as a fastening agent was explored. The mesophase of the materials was investigated through powder X-ray diffraction and TEM analysis (TEM) and N2 sorption studies. The TEM results revealed that the mesopores were created by the arrangement of ZrO2 NPs with sizes of 7.0-9.0nm and with broad interparticle pores. Moreover, the N2 sorption study confirmed the results. The surface chemical analysis was performed to estimate the distribution of Zr, O, and S in the sulfated ZrO2 matrices. The materials in this study displayed excellent catalytic activity in the biodiesel reaction for effective conversion of long-chain fatty acids to their methyl esters, and the maximum biodiesel yield was approximately 100%. The excellent heterogeneous catalytic activity could be attributed to the open framework, large surface area, presence of ample acidic sites located at the surface of the matrix, and high structural stability of the materials. The catalysts revealed a negligible loss of activity in the catalytic recycles.

Stoloniferins VIII-XII, resin glycosides, from Ipomoea stolonifera

Noda, Naoki,Takahashi, Naotsugu,Miyahara, Kazumoto,Yang, Chong-Ren

, p. 837 - 841 (1998)

Five new ether-soluble resin glycosides were isolated from whole plants of Ipomoea stolonifera. Their structures have been determined on the basis of chemical and spectral data. Similar to the resin glycosides previously isolated, all of them are monomers of a jalapinolic acid tetra- or penta- glycoside in which the sugar moiety is partially acylated by organic acids and also combined with the carboxy group of the aglycone to form a macrocyclic ester structure.

Lupeol-3-O-decanoate, a new triterpene ester from Cadaba farinosa Forssk. growing in Saudi Arabia

Al-Musayeib, Nawal M.,Mohamed, Gamal A.,Ibrahim, Sabrin R. M.,Ross, Samir A.

, p. 5297 - 5302 (2013)

A new triterpene ester (1) together with eight known compounds (2-9) were isolated from the leaves of Cadaba farinosa Forssk. Their chemical structures were established on the basis of physical, chemical, and spectroscopic methods (IR, 1D and 2D NMR, and mass spectral analyses) to be: lupeol-3-O-decanoate (1), lupeol (2), β-sitosterol (3), ursolic acid (4), 12-aminododecanoic (5), dillenetin-3-O-β-d-glucopyranoside (6), stachydrine (7), 3-hydroxy-stachydrine (8), and quercetin-3-O-β-d-glucopyranoside (9). That is the first report for the isolation of compound 5 from a plant source. Compounds 5, 6, and 9 were evaluated for their antioxidant activity.

AN 8-HYDROXYOCTADECA-CIS-11,14-DIENOIC ACID FROM MIRABILIS JALAPA SEED OIL

Ahmad, Mohammad Shamim,Rauf, Abdul,Mustafa, Jamal,Osman, Sheikh Mohammad

, p. 2247 - 2250 (1984)

A fatty acid, found as a minor component in the seed oil of Mirabilis jalapa, is shown to be the hitherto unknown 8-hydroxyoctadeca-cis-11,14-dienoic acid. - Key Word Index: Mirabilis jalapa; Nyctaginaceae; seed oil; 8-hydroxyoctadeca-cis-11,14-dienoic acid.

NEW BUTENOLIDES FROM THE GORGONIAN EUPLEXAURA FLAVA(NUTTING)

Kikuchi, Hiroyuki,Tsukitani, Yasumasa,Nakanishi, Hajime,Shimizu, Iwao

, p. 233 - 236 (1982)

Four new butanolides (1a-d) were isolated from the Japanese gorgonian Euplexaura flava(Nutting).The structures of these compounds were elucidated from spectral data and chemical reactions.

Carbon-carbon bond fission on oxidation of primary alcohols to carboxylic acids

Bekish, Andrei V.

, p. 3082 - 3085 (2012)

α-Carbon-carbon bond cleavage is shown to be a general side reaction accompanying the oxidation of unbranched primary alcohols to the corresponding carboxylic acids using HNO3, CrO3/H2SO 4/H2O/acetone, CrO3/CH3COOH, PDC/DMF, H5IO6/CrO3, KMnO4/H +, KMnO4/HO-, NiCl2/NaClO, TEMPO/PhI(OAc)2. Therefore, the product formed is always contaminated with a carboxylic acid containing one carbon atom less. Systems such as PhI(OAc)2/TEMPO or H5IO6/CrO 3/CH3CN reduce to a minimum the content of this impurity. Temperature, the order of reagent addition, and additives such as oxalic acid or cerium salts produce a profound effect on the formation of the undesirable impurity during the Jones oxidation of primary alcohols.

Ando,Tsukamoto

, p. 1031 (1974)

Isolation and characterization of the chemical constituents from Plumeria rubra

Akhtar, Nasim,Saleem, Muhammad,Riaz, Naheed,Ali, M. Shaiq,Yaqoob, Asma,Nasim, Faiz-Ul-Hassan,Jabbar, Abdul

, p. 291 - 298 (2013)

Rubranonoside (=7-O-α-l-rhamnopyranosyl-4′-O-β-d- glucopyranosylnaringenin; (1), a new flavanone glycoside, rubranin (=(2S,3S,4R)-2-{[(2R,16E)-2-hydroxyhexaeico-16-en]amino}octadecane-1,3, 4-triol-1-O-β-d-glucopyranoside; (2), a new sphingolipid, rubradoid (plumieridine-1-O-β-d-galactopyranoside; (3), a new iridoid galactoside, rubrajaleelol (4) and rubrajaleelic acid (5), two new nor-terpenoids together with known iridoids: 1-α-plumieride (6), plumieride p-Z-coumarate (7) and plumieride-p-E-coumarate (8) have been isolated from the EtOAc-soluble fraction of the MeOH extract of Plumeria rubra. Their structures were assigned from 1H, 13C NMR spectra and 2D NMR analyses (COSY, NOESY, HMQC and HMBC experiments) in combination with HRMS experiments and comparison with literature data of related compounds. All the isolates (1-8) were tested for their antioxidant, antiurease, cytotoxic and phytotoxic activities and were found almost inactive.

Convenient method for the synthesis of N-(ethyloxycarbonyl) ester derivatives from amino acids

Kanth,Periasamy

, p. 1523 - 1530 (1995)

Amino acids upon treatment with ethyl chloroformate in methanol in the presence of potassium carbonate give the corresponding N-(ethyloxycarbonyl) amino acid ester derivatives in good yields. These derivatives can be also synthesized by performing the reaction in THF in the presence of alcohols.

DITERPENES FROM THE LATEX OF EUPHORBIA BROTERI

a Jose Sexmero,Marcos, Isidro Sanchez

, p. 207 - 212 (1988)

Six polycyclic diterpenes have been isolated from the latex of Euphorbia broteri Daveau.Two had a tigliane skeleton: 12-O-(2Z,4E-octadienoyl)-4-deoxyphorbol-13,20-diacetate and 12-O-(2Z,4E-octadienoyl)-phorbol-13,20-diacetate and four an ingenane skeleton: 20-acetyl-ingenol-3-decadienoate, 3-O-tetradecanoyl-ingenol, 20-O-tetradecanoyl-ingenol and 5-O-tetradecanoyl-ingenol.The second and last two compounds are described as natural compounds for the first time.Their structures were established by spectroscopic methods, by chemical correlations and by H/H and C/H correlations in their 1H NMR and 13C NMR spectra.Key Word Index - Euphorbia broteri; Euphorbiaceae; latex; proinflammatory fractions; ingenol and phorbol mono-,di- and triesters; tetracyclic diterpenes.

Carboxylic Acid Reductase Can Catalyze Ester Synthesis in Aqueous Environments

Pongpamorn, Pornkanok,Kiattisewee, Cholpisit,Kittipanukul, Narongyot,Jaroensuk, Juthamas,Trisrivirat, Duangthip,Maenpuen, Somchart,Chaiyen, Pimchai

supporting information, p. 5749 - 5753 (2021/02/01)

Most of the well-known enzymes catalyzing esterification require the minimization of water or activated substrates for activity. This work reports a new reaction catalyzed by carboxylic acid reductase (CAR), an enzyme known to transform a broad spectrum of carboxylic acids into aldehydes, with the use of ATP, Mg2+, and NADPH as co-substrates. When NADPH was replaced by a nucleophilic alcohol, CAR from Mycobacterium marinum can catalyze esterification under aqueous conditions at room temperature. Addition of imidazole, especially at pH 10.0, significantly enhanced ester production. In comparison to other esterification enzymes such as acyltransferase and lipase, CAR gave higher esterification yields in direct esterification under aqueous conditions. The scalability of CAR catalyzed esterification was demonstrated for the synthesis of cinoxate, an active ingredient in sunscreen. The CAR esterification offers a new method for green esterification under high water content conditions.

Method of Preparing Aminoundecane Acid and 11-Aminoundecanoic Acid or Structural Isomer Thereof by Hydroformylation Reaction

-

Paragraph 0068; 0074-0095; 0119-0122, (2020/11/03)

The present invention relates to a method for preparing 11-aminoundecanoic acid or structural isomers thereof using a hydroformylation reaction. More particularly, the present invention is an eco-friendly method capable of preparing aminoundecanoic acid used as a monomer of polyamide and structural isomers thereof from an olefinic acid ester obtained through a metathesis reaction of oleic acid by means of hydroformylation, reductive amination reaction, and hydrolysis reaction, and capable of producing various polyamides having different physical properties according to a ratio of each isomer since the ratio of structural isomers can be adjusted according to a ligand.COPYRIGHT KIPO 2021

Structure determination of fatty acid ester biofuels via in situ cryocrystallisation and single crystal X-ray diffraction

Prathapa, Siriyara Jagannatha,Slabbert, Cara,Fernandes, Manuel A.,Lemmerer, Andreas

, p. 41 - 52 (2019/01/03)

In situ cryocrystallisation in combination with a zone-melting technique enabled the crystal structure determination of a homologous series of low-melting n-alkyl methyl esters Cn-1H2n+1CO2CH3, from methyl pentanoate (n = 5) to methyl tridecanoate (n = 13), by single crystal X-ray diffraction. Two isostructural groups were identified: the odd-numbered triclinic members (C9,11,13) and the even-numbered orthorhombic members (C8,10,12). All observed structural trends, similarities and differences in intermolecular contacts, including the odd-even effect observable in melting point behaviour and unit cell parameters, were easily visualised and described by 2D fingerprint plots generated from the calculated Hirshfeld surfaces, in combination with atom-atom Coulomb-London-Pauli (AA-CLP) lattice energy calculations.

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