125828-13-9

Basic information

• Product Name: Silane, dimethyl(1-oxodecyl)phenyl-
• CAS NO: 125828-13-9
• Molecular Formula: C18H30OSi
• Molecular Weight: 290.521
• Mol File: 125828-13-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Silane, dimethyl(1-oxodecyl)phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, dimethyl(1-oxodecyl)phenyl-(125828-13-9)
• EPA Substance Registry System: Silane, dimethyl(1-oxodecyl)phenyl-(125828-13-9)

Safety Data

• Hazardous Substances Data: 125828-13-9(Hazardous Substances Data)

Upstream product

• 3839-31-4 dimethyl(phenyl)silyllithium 
• 110-42-9 Methyl decanoate 
• 155397-14-1 1,1-bisdecan-1-ol 
• 125828-06-0 1-dimethyl(phenyl)silyldecan-1-ol 

Downstream Products

• 110-42-9 Methyl decanoate 
• 1975-78-6 n-decanenitrile 
• 142981-58-6 decanoylphenyldimethylsilane tosylhydrazone 

Relevant articles and documents

Synthesis of Acylsilanes from Amides and Esters, and the Selective Oxidation of α-Silyl Alcohols to Aldehydes

The acylsilanes 2 can easily be made directly from the dimethylamides 3 by treatment with phenyldimethylsilyllithium.They can also be made in two steps from the esters 4 using 2 equiv. of phenyldimethylsilyllithium followed by oxidation of the disilyl alcohols 5 with PDC.The disilyl alcohols 5 can be used as intermediates in the conversion of esters into aldehydes without recourse to hydride reagents, by monodesilylation, using a Brook rearrangement, followed by oxidation and selective removal of the silyl group, using chromium trioxide in DMSO.