1430962-42-7

Basic information

• Product Name: acetophenone N,N-(benzyl(pent-4-en-1-yl)carbamoyl) oxime
• Synonyms: acetophenone N,N-(benzyl(pent-4-en-1-yl)carbamoyl) oxime
• CAS NO: 1430962-42-7
• Molecular Weight: 336.434
• Mol File: 1430962-42-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: acetophenone N,N-(benzyl(pent-4-en-1-yl)carbamoyl) oxime(CAS DataBase Reference)
• NIST Chemistry Reference: acetophenone N,N-(benzyl(pent-4-en-1-yl)carbamoyl) oxime(1430962-42-7)
• EPA Substance Registry System: acetophenone N,N-(benzyl(pent-4-en-1-yl)carbamoyl) oxime(1430962-42-7)

Safety Data

• Hazardous Substances Data: 1430962-42-7(Hazardous Substances Data)

Upstream product

• 613-91-2 acetophenone oxime 
• 1430962-71-2 N-benzyl-N-(pent-4-en-1-yl)-1H-imidazole-1-carboxamide 
• 54436-58-7 N-benzylpent-4-en-1-amine 

Downstream Products

• 774-91-4 1-benzyl-2-methylpyrrolidine 
• 1430963-05-5 C₂₀H₂₄N₂ 
• 13280-20-1 1-phenylethanimine 
• 98-86-2 acetophenone 
• 729-43-1 acetophenonazine 
• 14428-98-9 N-benzyl-N-(1-phenylethylidene)amine 

Relevant articles and documents

Dissociation or cyclization: Options for a triad of radicals released from oxime carbamates

A set of oxime carbamates having N-alkyl and N,N-dialkyl substituents were prepared via carbonyldiimidazole intermediates. It was shown by EPR spectroscopy that they underwent clean homolysis of their N-O bonds upon UV photolysis. During photolysis of acetophenone O-allylcarbamoyl oxime, the corresponding oxazolidin-2-onylmethyl radical was detected by EPR spectroscopy, providing the first evidence that N-monosubstituted carbamoyloxyl radicals can hold their structural integrity. N,N-Disubstituted carbamoyloxyl radicals dissociated rapidly at the lowest accessible temperatures. Above room temperature, both types of oxime carbamate acted as selective new precursors for aminyl and iminyl radicals. Rate parameters were measured for 5-exo cyclization of N-benzyl-N-pent-4-enylaminyl radicals; the rate constant was smaller than for C-centered and O-centered analogues. Oxime carbamates derived from the volatile diethylamine afforded aryliminyl radicals that proved convenient for phenanthridine preparations.