1431387-07-3Relevant academic research and scientific papers
Oxidative esterification of aldehydes using a recyclable oxoammonium salt
Kelly, Christopher B.,Mercadante, Michael A.,Wiles, Rebecca J.,Leadbeater, Nicholas E.
, p. 2222 - 2225 (2013/06/05)
A simple, high yielding, rapid route for the oxidative esterification of a wide range aldehydes to hexafluoroisopropyl (HFIP) esters using the oxoammonium salt 4-acetylamino-2,2,6,6-tetramethylpiperidine-1-oxoammonium tetrafluoroborate (1a) is reported. These esters can be readily transformed into a variety of other functional groups. The spent oxidant (1b) can be recovered and conveniently reoxidized to regenerate the oxoammonium salt, 1a.
