88037-32-5

Basic information

• Product Name: methyl 2,3,4-tri-O-benzoyl-β-D-glucopyranoside
• Synonyms: methyl 2,3,4-tri-O-benzoyl-β-D-glucopyranoside
• CAS NO: 88037-32-5
• Molecular Weight: 506.509
• Mol File: 88037-32-5.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: methyl 2,3,4-tri-O-benzoyl-β-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2,3,4-tri-O-benzoyl-β-D-glucopyranoside(88037-32-5)
• EPA Substance Registry System: methyl 2,3,4-tri-O-benzoyl-β-D-glucopyranoside(88037-32-5)

Safety Data

• Hazardous Substances Data: 88037-32-5(Hazardous Substances Data)

Upstream product

• 143249-54-1 Methyl 2,3,4-tri-O-benzoyl-6-O-tert-butyldiphenylsilyl-β-D-glucopyranoside 
• 92516-59-1 methyl 6-azido-2,3,4-tri-O-benzoyl-6-deoxy-α-D-idopyranoside 
• 143249-53-0 methyl 6-O-(tert-butyldiphenylsilyl)-β-D-glucopyranoside 
• 98-88-4 benzoyl chloride 
• 128844-03-1 methyl-6-O-(dimethyl-(1‘, 1‘, 2‘-trimethylpropyl)-silyl)-β-D-glucopyranoside 
• 67412-01-5 Methyl 6-O-triphenylmethyl-β-D-glucopyranoside 
• 709-50-2 methyl beta-D-glucopyranoside 
• 3396-99-4 methyl α-D-galactopyranoside 
• 1824-94-8 methyl beta-D-galactopyranoside 
• 127073-07-8 methyl 2,3,4-tri-O-benzoyl-6-O-chloroacetyl-β-D-galactopyranoside 
• 127073-08-9 methyl 6-O-bromoacetyl-α-D-galactopyranoside 
• 127073-06-7 methyl 6-O-bromoacetyl-β-D-galactopyranoside 
• 102518-21-8 methyl 2,3-di-O-benzoyl-β-D-glucopyranoside 
• 910887-49-9 methyl 2,3,4-tri-O-benzoyl-6-trityl-β-D-glucopyranoside 

Downstream Products

• 553662-29-6 methyl 2,3-di-O-benzoyl-4-deoxy-6-aldehydo-β-L-erythro-hex-4-enopyranoside 
• 1352442-78-4 methyl 6-O-acetyl-2-O-benzyl-3,5-O-(di-tertbutylsilanediyl)-α-D-galactofuranosyl-(1->6)-2,3,4-tri-O-benzoyl-α-D-mannopyranoside 
• 144102-40-9 C₅₈H₆₂O₁₆ 
• 144102-40-9 C₅₈H₆₂O₁₆ 
• 143249-57-4 Methyl O-(2,3,4-tri-O-benzoyl-6-O-bromoacetyl-β-D-galactopyranosyl)-(1->6)-2,3,4-tri-O-benzoyl-β-D-glucopyranoside 
• 143249-61-0 Methyl O-(2,3,4-tri-O-benzoyl-6-O-bromoacetyl-β-D-galactopyranosyl)-(1->6)-O-(2,3,4-tri-O-benzoyl-β-D-glucopyranosyl)-(1->6)-2,3,4-tri-O-benzoyl-β-D-glucopyranoside 
• 127099-62-1 methyl O-(2,3,4-tri-O-benzoyl-6-O-chloroacetyl-β-D-glucopyranosyl)-(1->6)-2,3,4-tri-O-benzoyl-β-D-glucopyranoside 

Relevant articles and documents

Visible-Light-Mediated, Chemo- and Stereoselective Radical Process for the Synthesis of C-Glycoamino Acids

An approach for efficient synthesis of C-glycosyl amino acids is described. Different from typical photoredox-catalyzed reactions of imines, the new process follows a pathway in which α-imino esters serve as electrophiles in chemoselective addition reactions with nucleophilic glycosyl radicals. The process is highlighted by the mild nature of the reaction conditions, the highly stereoselectivity attending C-C bond formation, and its applicability to C-glycosylations using both armed and disarmed pentose and hexose derivatives.

Studies on the substrate specificity of a GDP-mannose pyrophosphorylase from Salmonella enterica

A series of methoxy and deoxy derivatives of mannopyranose-1-phosphate (Manp-1P) were chemically synthesized, and their ability to be converted into the corresponding guanosine diphosphate mannopyranose (GDP-Manp) analogues by a pyrophosphorylase (GDP-ManPP) from Salmonella enterica was studied. Evaluation of methoxy analogues demonstrated that GDP-ManPP is intolerant of bulky substituents at the C-2, C-3, and C-4 positions, in turn suggesting that these positions are buried inside the enzyme active site. Additionally, both the 6-methoxy and 6-deoxy Manp-1P derivatives are good or moderate substrates for GDP-ManPP, thus indicating that the C-6 hydroxy group of the Manp-1P substrate is not required for binding to the enzyme. When taken into consideration with other previously published work, it appears that this enzyme has potential utility for the chemoenzymatic synthesis of GDP-Manp analogues, which are useful probes for studying enzymes that employ this sugar nucleotide as a substrate.

Regioselective C-6 hydrolysis of methyl O-benzoyl-pyranosides catalysed by candida rugosa lipase

Hydrolysis of six methyl O-benzoyl-pyranosides has been investigated using Candida rugosa lipase in dioxane/buffer mixtures. The lipase catalysed the hydrolysis of all substrates in a regiospecific manner at C-6, The rate of reaction was dependent on pyra