1432519-06-6

Basic information

• Product Name: 1-[5-butyl-2-oxo-3-(phenylselanyl)oxolan-3-yl]-4,4-bis-(phenylsulfanyl)butyl acetate
• Synonyms: 1-[5-butyl-2-oxo-3-(phenylselanyl)oxolan-3-yl]-4,4-bis-(phenylsulfanyl)butyl acetate
• CAS NO: 1432519-06-6
• Molecular Weight: 627.727
• Mol File: 1432519-06-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-[5-butyl-2-oxo-3-(phenylselanyl)oxolan-3-yl]-4,4-bis-(phenylsulfanyl)butyl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: 1-[5-butyl-2-oxo-3-(phenylselanyl)oxolan-3-yl]-4,4-bis-(phenylsulfanyl)butyl acetate(1432519-06-6)
• EPA Substance Registry System: 1-[5-butyl-2-oxo-3-(phenylselanyl)oxolan-3-yl]-4,4-bis-(phenylsulfanyl)butyl acetate(1432519-06-6)

Safety Data

• Hazardous Substances Data: 1432519-06-6(Hazardous Substances Data)

Upstream product

• 1432519-03-3 5-butyl-3-[1-hydroxy-4,4-bis(phenylsulfanyl)butyl]-3-(phenylselanyl)oxolan-2-one 
• 75-36-5 acetyl chloride 
• 371-42-6 4-Fluorothiophenol 
• 1432519-38-4 1-({3-chloro-1-[(4-fluorophenyl)sulfanyl]propyl}sulfanyl)-4-fluorobenzene 
• 1432518-82-5 4,4-bis[(4-fluorophenyl)sulfanyl]butanenitrile 
• 1432518-85-8 4,4-bis[(4-fluorophenyl)sulfanyl]butanal 
• 104-50-7 gamma-octalactone 
• 1432518-81-4 5-butyl-3-(phenylselanyl)oxolan-2-one 

Downstream Products

• 1432519-05-5 4,4-bis(benzenesulfonyl)-1-(5-butyl-2-oxo-2,5-dihydrofuran-3-yl)butyl acetate 

Relevant articles and documents

Asymmetric synthesis of carbocycles: Use of intramolecular conjugate displacement

Intramolecular conjugate displacement (ICD), the process illustrated in eqn (1), has been applied to the Morita-Baylis-Hillman adducts formed from (5S)-5-(l-menthyloxy)-2(5H)-furanone and aldehydes that are substituted in the γ- or δ-position by geminal phenylthio groups. When the initial Morita-Baylis-Hillman alcohols are acetylated and oxidized to geminal sulfones, deprotonation causes ring closure by ICD (2.5→2.6). Hydrogenation, DIBAL-H reduction and desulfonylation releases an optically pure carbocycle. The Royal Society of Chemistry 2013.