143256-97-7Relevant academic research and scientific papers
Asymmetric multipoint control by palladium-catalyzed diastereoselective tandem carbon-carbon bond formation
Torii,Okumoto,Kotani,Nakayasu,Ozaki
, p. 3503 - 3506 (1992)
Palladium-catalyzed diastereo-differentiative tandem connection of cis-alkenyl iodide, cyclic fragment, and terminal acetylene was executed. The discrimination of the diastereotopic face and olefinic carbons of norbornene was achieved with accompanying isomerization of the cis-geometry of the olefin to trans in good yields.
