143328-35-2Relevant academic research and scientific papers
Toward Dendritic Two-Dimensional Polycarbenes: Syntheses of 'Starburst'-Type Nona- and Dodecadiazo Compounds and Magnetic Study of Their Photoproducts
Matsuda, Kenji,Nakamura, Nobuo,Inoue, Katsuya,Koga, Noboru,Iwamura, Hiizu
, p. 1483 - 1494 (2007/10/03)
'Starburst'-type nona- and dodecadiazo compounds were designed and synthesized by using the cyclotrimerization of ethynyl ketones as a key step. Construction of the larger dodecadiazo compounds was facilitated by using a trimethylsilyl protecting group fo
APPROACHES TO SUPERPARAMAGNETIC POLYCARBENES AND POLYNITRENES
Iwamura, Hiizu,Nakamura, Nobuo,Koga, Noboru,Sasaki, Shigeru
, p. 207 - 212 (2007/10/02)
Poly(m-phenylenemethynyls) and other conjugated polymers to which photolabile diazo or azido groups are attached in every repeating unit have been synthesized.When photolyzed and studied in situ by means of a Faraday balance equipped with a light guide at cryogenic temperatures, the hexa- and nonacarbenes obtained by stepwise synthesis were found to be in S = 6 and 9 ground states, respectively.Attempts to synthesize real polymer samples capable of showing S = 102 ca. 3 were made.These materials would serve as prototypes for organic optomagnetic recording devices.
