143328-36-3Relevant academic research and scientific papers
Exploratory and Mechanistic Studies of the Trimerization Reaction of Benzoylacetylenes in the Presence of Secondary Amine
Matsuda, Kenji,Nakamura, Nobuo,Iwamura, Hiizu
, p. 1765 - 1768 (2007/10/02)
A variety of benzoylacetylenes are trimerized to give the corresponding 1,3,5-tribenzoylbenzenes when heated with a catalytic amount of diethylamine.A large amount of diethylamine gives γ-(diethylamino)propenoylbenzene at the expense of 1,3,5-tribenzoylbe
APPROACHES TO SUPERPARAMAGNETIC POLYCARBENES AND POLYNITRENES
Iwamura, Hiizu,Nakamura, Nobuo,Koga, Noboru,Sasaki, Shigeru
, p. 207 - 212 (2007/10/02)
Poly(m-phenylenemethynyls) and other conjugated polymers to which photolabile diazo or azido groups are attached in every repeating unit have been synthesized.When photolyzed and studied in situ by means of a Faraday balance equipped with a light guide at cryogenic temperatures, the hexa- and nonacarbenes obtained by stepwise synthesis were found to be in S = 6 and 9 ground states, respectively.Attempts to synthesize real polymer samples capable of showing S = 102 ca. 3 were made.These materials would serve as prototypes for organic optomagnetic recording devices.
