143377-02-0

Upstream product

• 582-52-5 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 119403-65-5 6-azido-6-deoxy-1,2-O-isopropylidene-3-O-methanesulfonyl-α-D-allofuranose 
• 147429-00-3 Methanesulfonic acid (3aR,5R,6R,6aR)-5-((S)-2-bromo-1-hydroxy-ethyl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl ester 
• 84730-20-1 3,6-epimino-3,6-dideoxy-1,2-O-isopropylidene-α-D-glucofuranose 
• 84730-21-2 N-benzyloxycarbonyl-3,6-dideoxy-3,6-imino-1,2-O-isopropylidene-α-D-glucofuranose 
• 98944-20-8 (1R,3R,7R,8S)-9-<(benzyloxy)carbonyl>-5,5-dimethyl-2,4,6-trioxa-9-azatricyclo<6.3.0.0^3,7>undecane 
• 64993-88-0 1,2-O-isopropylidene-3-O-methanesulfonyl-α-D-allofuranose 
• 14728-80-4 1,2:5,6-di-O-isopropylidene-3-O-(methylsulphonyl)-α-D-allofuranose 
• 2847-00-9 1,2:5,6-di-O-isopropylidene-α-D-hexofuran-3-ulose 
• 14686-89-6 (1,2:5,6)-di-O-isopropylidene-D-gulose 
• 98944-26-4 (-)-(2S,3R)-1-<(benzyloxy)carbonyl>-2-<(S)-1-(benzyloxy)prop-2-enyl>-3-hydroxypyrrolidine 

Downstream Products

• 37878-19-6 detoxin D&%1 
• 143367-59-3 (S)-1-<(2R,3R)-3-acetoxy-1-<(benzyloxy)carbonyl>-2-pyrrolidinyl>-1-benzyloxy-3-<(tert-butyldimethylsilyl)oxy>-propane 
• 143367-60-6 (S)-1-<(2R,3R)-3-acetoxy-1--2-pyrrolidinyl>-1-benzyloxy-3-<(tert-butyldimethylsilyl)oxy>-propane 

Relevant academic research and scientific papers

Total Synthesis of (-)-Detoxin D1

An efficient stereocontrolled total synthesis of (-)-detoxin D1, the most active component of the detoxin complex, is described.

Total synthesis of (+)-valyldetoxinine and (-)-detoxin D1

The detoxin complex, metabolites produced by Streptomyces caespitosus var. detoxicus 7072 GC1, is a selective antagonist of the antibiotic blasticidin S. Two approaches toward the total synthesis of (+)-valyldetoxinine and (-)-detoxin D1/