1433996-30-5

Basic information

• Product Name: (E)-tert-butyldimethyl((6-phenylhex-5-en-1-yl)oxy)silane
• Synonyms: (E)-tert-butyldimethyl((6-phenylhex-5-en-1-yl)oxy)silane
• CAS NO: 1433996-30-5
• Molecular Weight: 290.521
• Mol File: 1433996-30-5.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (E)-tert-butyldimethyl((6-phenylhex-5-en-1-yl)oxy)silane(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-tert-butyldimethyl((6-phenylhex-5-en-1-yl)oxy)silane(1433996-30-5)
• EPA Substance Registry System: (E)-tert-butyldimethyl((6-phenylhex-5-en-1-yl)oxy)silane(1433996-30-5)

Safety Data

• Hazardous Substances Data: 1433996-30-5(Hazardous Substances Data)

Upstream product

• 1080-32-6 O,O-diethyl benzylphosphonate 
• 53575-08-9 diethyl 1-naphthylmethylphosphonate 
• 100-58-3 phenylmagnesium bromide 
• 502-44-3 hexahydro-2H-oxepin-2-one 
• 17851-49-9 5-hydroxypentyl phenyl ketone 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 13038-15-8 (E)-6-hydroxy-hex-2-enoic acid ethyl ester 
• 193948-52-6 (E)-ethyl 6-((tert-butyldimethylsilyl)oxy)hex-2-enoate 
• 98897-64-4 (E)-6-[(tert-butyldimethylsilyl)oxy]-2-hexen-1-ol 
• 1044869-80-8 (E)-tert-butyl((6-methoxyhex-4-en-1-yl)oxy)dimethylsilane 
• 4406-72-8 2-phenyl[1,3,2]dioxaborolane 
• 85807-84-7 tert-butyl(5-hexenyloxy)dimethylsilane 
• 100-42-5 styrene 

Downstream Products

• 17924-66-2 phenyl-6 hexene-5 ol-1 (E) 

Relevant articles and documents

Rhodium-Catalyzed Deoxygenation and Borylation of Ketones: A Combined Experimental and Theoretical Investigation

The rhodium-catalyzed deoxygenation and borylation of ketones with B2pin2 have been developed, leading to efficient formation of alkenes, vinylboronates, and vinyldiboronates. These reactions feature mild reaction conditions, a broad substrate scope, and excellent functional-group compatibility. Mechanistic studies support that the ketones initially undergo a Rh-catalyzed deoxygenation to give alkenes via boron enolate intermediates, and the subsequent Rh-catalyzed dehydrogenative borylation of alkenes leads to the formation of vinylboronates and diboration products, which is also supported by density functional theory calculations.

Conjugated Microporous Polymer as Heterogeneous Ligand for Highly Selective Oxidative Heck Reaction

A series of pyridine-type ligands containing C C bonds were designed and synthesized for selective oxidative Heck reaction. These ligands were utilized as functional units and integrated into the skeleton of conjugated microporous polymers. 6,6′-diiodo-2,2′-bipyridine and 1,3,5-triethynylbenzene were polycondensed via Sonogashira cross-coupling strategy to afford CMP-1 material. The resultant CMP-1 was used as a heterogeneous catalytic ligand for the PdII-catalyzed oxidative Heck reaction with high linear selectivity. The linear selectivity of CMP-1 is about 30 times higher than that of bipyridine-based monomer ligand. This work opens a new front of using CMP as an intriguing platform for developing highly efficient catalysts in controlling the regioselectivity in organic reactions.

Synthesis of a structural analogues of the cinchona alkaloids

Five olefins, each possessing an aryl (Ar) group, an aliphatic moiety, and a protected amino group as N-Teoc (-CO2(CH2)TMS) or N3 at the aliphatic end, were converted to the corresponding epoxides with high ee. The amino g