1434248-16-4

Basic information

• Product Name: (2-(benzo[d]thiazol-2-yl)-4-methylphenyl)(phenyl)methanone
• Synonyms: (2-(benzo[d]thiazol-2-yl)-4-methylphenyl)(phenyl)methanone
• CAS NO: 1434248-16-4
• Molecular Weight: 329.422
• Mol File: 1434248-16-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (2-(benzo[d]thiazol-2-yl)-4-methylphenyl)(phenyl)methanone(CAS DataBase Reference)
• NIST Chemistry Reference: (2-(benzo[d]thiazol-2-yl)-4-methylphenyl)(phenyl)methanone(1434248-16-4)
• EPA Substance Registry System: (2-(benzo[d]thiazol-2-yl)-4-methylphenyl)(phenyl)methanone(1434248-16-4)

Safety Data

• Hazardous Substances Data: 1434248-16-4(Hazardous Substances Data)

Upstream product

• 1211-32-1 2-(m-tolyl)benzo[d]thiazole 
• 100-51-6 benzyl alcohol 
• 100-52-7 benzaldehyde 
• 108-88-3 toluene 

Relevant articles and documents

Palladium-catalyzed oxidative ortho-acylation of 2-arylbenzoxazoles and 2-arylbenzothiazoles with toluene derivatives

A palladium-catalyzed oxidative ortho-acylation of 2-arylbenzoxazoles and 2-arylbenzothiazoles using TBHP as oxidant was developed, in which readily available toluene derivatives were used as the in situ generated acyl sources. This reaction afforded the desired products in moderate to good yields, and exhibited excellent regioselectivity. The plausible mechanism was also proposed.

Palladium-catalyzed ortho-acylation of 2-arylbenzoxazoles and 2-arylbenzothiazoles using arylmethyl alcohols as the acyl source

A facile and efficient way for the synthesis of the acylated 2-arylbenzoxazoles and 2-arylbenzothiazoles by heterocycle-directed ortho-acylation was developed. This reaction was performed in chlorobenzene, using arylmethyl alcohols and tert-butyl hydroperoxide (TBHP) as the easily accessible acyl source and the oxidant, respectively, affording the desired products in moderate to good yields.