14353-88-9Relevant articles and documents
Simple direct synthesis of [bis(trifluoroacetoxy)iodo]arenes
Page, T. Keri,Wirth, Thomas
, p. 3153 - 3155 (2006)
A modified procedure for the direct synthesis of hypervalent [bis(trifluoroacetoxy)iodo]arenes is described. It avoids the use of hazardous reagents with the workup being only an aqueous extraction. Georg Thieme Verlag Stuttgart.
Alternative Strategies with Iodine: Fast Access to Previously Inaccessible Iodine(III) Compounds
Hokamp, Tobias,Mollari, Leonardo,Wilkins, Lewis C.,Melen, Rebecca L.,Wirth, Thomas
supporting information, p. 8306 - 8309 (2018/06/29)
Non-iodinated arenes can be easily and selectively converted into (diacetoxyiodo)arenes in a single step under mild conditions by using iodine triacetates as reagents. The oxidative step is decoupled from the synthesis of hypervalent iodine(III) reagents, which can now be prepared conveniently in a one-pot synthesis for subsequent reactions without prior purification. The chemistry of iodine triacetates was also expanded to heteroatom ligand exchanges to form novel inorganic hypervalent iodine compounds.
Facile One-Pot Synthesis of Diaryliodonium Salts from Arenes and Aryl Iodides with Oxone
Soldatova, Natalia,Postnikov, Pavel,Kukurina, Olga,Zhdankin, Viktor V.,Yoshimura, Akira,Wirth, Thomas,Yusubov, Mekhman S.
, p. 18 - 20 (2017/02/10)
A straightforward synthesis of diaryliodonium salts is achieved by using Oxone as the stoichiometric oxidant. Slow addition is the key to obtaining good yields and purities of the reaction products, which are highly useful reagents in many different areas of organic synthesis.
Fluorine-containing diaryliodonium salt and application thereof
-
Paragraph 0030; 0031; 0032; 0033; 0034, (2017/01/02)
The invention relates to fluorine-containing diaryliodonium salt as well as a preparation method and an application thereof. The fluorine-containing diaryliodonium salt has a structure represented as a formula I and is taken as an arylation reagent. The fluorine-containing diaryliodonium salt has the advantages that the preparation is easy, when the fluorine-containing diaryliodonium salt is applied to an arylation reaction, the arylation reaction condition is relatively mild, the selectivity of an arylation product is good and the like; in the formula I shown in the specification, R1 represents an aromatic ring group or a heteroaromatic ring group or represents a substituted aromatic ring group or a substituted heteroaromatic ring group, and Y represents a univalent organic or inorganic acid radical anion.