14357-51-8

Basic information

• Product Name: Carbamic acid, (4-nitrophenyl)-, 1-methylethyl ester
• CAS NO: 14357-51-8
• Molecular Formula: C10H12N2O4
• Molecular Weight: 224.216
• Mol File: 14357-51-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Carbamic acid, (4-nitrophenyl)-, 1-methylethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic acid, (4-nitrophenyl)-, 1-methylethyl ester(14357-51-8)
• EPA Substance Registry System: Carbamic acid, (4-nitrophenyl)-, 1-methylethyl ester(14357-51-8)

Safety Data

• Hazardous Substances Data: 14357-51-8(Hazardous Substances Data)

Upstream product

• 100-28-7 4-Nitrophenyl isocyanate 
• 67-63-0 isopropyl alcohol 
• 122-42-9 carbamic acid, phenyl-, 1-methylethyl ester 
• 2621-73-0 ethyl 4-nitrophenylcarbamate 
• 51028-38-7 (4-nitro-phenyl)-carbamoyl chloride 
• 303158-02-3 (4-nitroso-phenyl)-carbamic acid isopropyl ester 
• 16135-31-2 p-nitroformanilide 

Downstream Products

• 629648-18-6 (4-acetylamino-phenyl)-carbamic acid isopropyl ester 
• 35198-91-5 2-acetamido-5-isopropoxycarbonylamino-1-nitrobenzene 
• 7038-94-0 (4-nitro-phenyl)-oxazolidinetrione 
• 30694-25-8 N-(4-aminophenyl)carbamic acid isopropyl ester 

Relevant articles and documents

Clay-Catalyzed Nitration of a Carbamate Fungicide Diethofencarb

The unique nitration of the carbamate fungicide diethofencarb (Powmyl, isopropyl 3,4-diethoxycarbanilate) was examined in 14 Japanese soils and three types of clays under the aerobic conditions using the 14C-Iabeled compound. Nitration at the 6

The Phthalimidomethyl Rearrangement

The discovery of a new acid-catalysed monodentate N -> C aromatic rearrangement, namely the phthalimidomethyl rearrangement, is reported.In this rearrangement, discovered during the reaction of N-hydroxymethylphthalimide with certain alkyl N-(4-nitrophenyl)carbamates in concentrated sulfuric acid solution, the phthalimidomethyl group migrates from its initial location on the nitrogen atom of the carbamate function to a carbon atom of the nitrophenyl group.Evidence, provided by an appropriate 'crossover' experiment, indicates that the rearrangement is intermolecular.Hindered rotation about the N(carbamoyl)-aryl bond of the N-phthalimidomethyl derivatives of both ethyl and methyl N-(2,4-dinitrophenyl)carbamate is reported.