14360-83-9Relevant academic research and scientific papers
The Reaction of some Azides with an Anionic Phosphorus(III) Complex
Baceiredo, Antoine,Bertrand, Guy,Majoral, Jean-Pierre,Dillon, Keith B.
, p. 562 - 563 (2007/10/02)
The first example of a Staudinger reaction involving an anionic phosphorus(III) species is reported; the (31)P chemical shift and reactivity of the resulting product indicate the formation of a novel iminophosphoranide(V).
PHOTOLYTIC REARRANGEMENT OF PHOSPHORUS AZIDE : EVIDENCE FOR A TRANSIENT METAPHOSPHONIMIDATE.
Bertrand, Guy,Majoral, Jean-Pierre,Baceiredo, Antoine
, p. 5015 - 5018 (2007/10/02)
Photolysis of the oxide of diphenylphosphine azide gives rise to a transient metaphisphonimidate, a new tricoordinated pentavalent phosphorus compound.Evidence for this species was given by trapping reactions on a variety of substrates.
