143633-96-9Relevant academic research and scientific papers
Reductive Cyclization of Ester-Containing Enynes with a Practical Titanocene Reagent. Synthesis of Bicyclic Cyclopentenones and Iminocyclopentenes
Grossman, Robert B.,Buchwald, Stephen L.
, p. 5803 - 5805 (1992)
The combination of Cp2TiCl2 with 2 equiv of EtMgBr provides an effective reagent for the reductive cyclization of enynes, including ester-containing enynes, to bicyclic titanacyclopentenes.These metallacycles may then be transformed into bicyclic cyclopen
