Journal of Organic Chemistry p. 5803 - 5805 (1992)
Update date:2022-07-30
Topics:
Grossman, Robert B.
Buchwald, Stephen L.
The combination of Cp2TiCl2 with 2 equiv of EtMgBr provides an effective reagent for the reductive cyclization of enynes, including ester-containing enynes, to bicyclic titanacyclopentenes.These metallacycles may then be transformed into bicyclic cyclopen
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