143918-74-5Relevant academic research and scientific papers
Decomposition of 2-diazo-1,3-diketones: Stereocontrol of the mechanism
Nikolaev, Valerij A.
, p. 4483 - 4486 (1992)
Complete "inversion" of alkyl to aryl migratory tendency in Wolff rearrangement of diazodiketones with Z,Z-conformation was revealed by comparing decomposition behavior of the planar diazo tetralindione with its twisted acyclic analogues. Dramatic change
