1439386-58-9Relevant academic research and scientific papers
Ni-Catalyzed Denitrogenative Cross-Coupling of Benzotriazinones and Cyclopropanols: An Easy Access to Functionalized β-Aryl Ketones
Li, Jincan,Zheng, Yan,Huang, Mingxian,Li, Wanfang
supporting information, p. 5020 - 5024 (2020/07/03)
A novel Ni-catalyzed denitrogenative cross-coupling between benzotriazinones and cyclopropanols is reported herein. This neoteric reactivity allows for the convenient synthesis of β-(o-amido)aryl ketones from readily available starting materials with good yields (up to 93percent) and general substrate scope.
Palladium-Catalyzed Hydroalkylation of Alkynes with Cyclopropanols: Access to γ,δ-Unsaturated Ketones
Liu, Hao,Fu, Zhiyuan,Gao, Shang,Huang, Yue,Lin, Aijun,Yao, Hequan
supporting information, p. 3171 - 3175 (2018/08/01)
A palladium-catalyzed hydroalkylation of alkynes with cyclopropanols has been developed. This reaction provided a straightforward way to the synthesis of γ,δ-unsaturated ketones in moderate to good yields, exhibiting high atom economy and Z/E selectivity. Deuterated tri-substituted alkenes could also be expediently produced by using deuterium oxide as a co-solvent. (Figure presented.).
Palladium-catalyzed cross-coupling of cyclopropanol-derived ketone homoenolates with aryl bromides
Rosa, David,Orellana, Arturo
supporting information, p. 5420 - 5422 (2013/06/27)
The cross-coupling reaction of cyclopropanol-derived ketone homoenolates bearing β-hydrogens with aryl and hetaryl bromides has been achieved for the first time. This reaction is high yielding, is broad in scope and uses a simple catalytic system. Notably, the proposed palladium homoenolates do not undergo β-hydride elimination to the corresponding α,β- unsaturated ketones.
