14399-84-9

Basic information

• Product Name: 2-Propenethioamide, 3-phenyl-
• CAS NO: 14399-84-9
• Molecular Formula: C9H9NS
• Molecular Weight: 163.243
• Mol File: 14399-84-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2-Propenethioamide, 3-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenethioamide, 3-phenyl-(14399-84-9)
• EPA Substance Registry System: 2-Propenethioamide, 3-phenyl-(14399-84-9)

Safety Data

• Hazardous Substances Data: 14399-84-9(Hazardous Substances Data)

Upstream product

• 4360-47-8 cinnamonitrile 
• 621-79-4 cinnamamide 
• 102-92-1 cinnamoyl chloride 
• 64-17-5 ethanol 
• 7783-06-4 hydrogen sulfide 
• 7664-41-7 ammonia 

Downstream Products

• 1885-38-7 cinnamic nitrile 
• 24840-05-9 (Z)-cinnamonitrile 
• 4360-47-8 cinnamonitrile 
• 1450722-78-7 isonicotinic acid N'-(1-amino-1-mercapto-3-phenyl-propen-1-yl)-hydrazide 
• 57182-78-2 Thiocinnamoylisocyanat 
• 116758-78-2 [4-(4-Bromo-phenyl)-2-((E)-styryl)-thiazol-5-yl]-acetic acid 
• 116758-77-1 [4-(4-Chloro-phenyl)-2-((E)-styryl)-thiazol-5-yl]-acetic acid 
• 116758-76-0 [4-(4-Fluoro-phenyl)-2-((E)-styryl)-thiazol-5-yl]-acetic acid 
• 116758-79-3 [2-((E)-Styryl)-4-p-tolyl-thiazol-5-yl]-acetic acid 
• 116758-75-9 [4-Phenyl-2-((E)-styryl)-thiazol-5-yl]-acetic acid 
• 107611-13-2 6-chloro-2-trans-styryl-benzothiazole 
• 57182-74-8 5-Styryl-1,2,4-dithiazol-3-on 
• 621-79-4 cinnamamide 
• 77358-40-8 2-Styryl-4,5-thiazolindion 

Relevant articles and documents

Aerobic Visible-Light Induced Intermolecular S?N Bond Construction: Synthesis of 1,2,4-Thiadiazoles from Thioamides under Photosensitizer-Free Conditions

Aerobic visible-light induced intermolecular S?N bond construction has been achieved without the addition of photosensitizer, metal, or base. With this strategy, 1,2,4-thiadiazoles can be obtained from thioamides. Preliminary mechanistic investigation suggested that the excited state of thioamides undergoes a single-electron-transfer (SET) process to afford thioamidyl radicals, which can be further transformed into a 1,2,4-thiadiazole through desulfurization and oxidative cyclization. The reaction has good functional group tolerance and represents a green method for the construction of S?N bonds.

Use of carbon-sulfur cathodes in electro-organic chemistry - Part 2 - Reactions with activated alkenes; evidence for a vicarious substitution specific of this type of electrode.

The sulfur-carbon electrode, used as a cathode, appears to be an excellent source of nucleophiles which are good sulfuration reagents towards alkenes not substituted by leaving groups.However, the electrochemical reactions are often complex.It should be w