144067-40-3

Basic information

• Product Name: 3-Cyclohexene-1-carboxaldehyde, 3-[(acetyloxy)methyl]-2,2,4-trimethyl-
• CAS NO: 144067-40-3
• Molecular Formula: C13H20O3
• Molecular Weight: 224.3
• Mol File: 144067-40-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 3-Cyclohexene-1-carboxaldehyde, 3-[(acetyloxy)methyl]-2,2,4-trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Cyclohexene-1-carboxaldehyde, 3-[(acetyloxy)methyl]-2,2,4-trimethyl-(144067-40-3)
• EPA Substance Registry System: 3-Cyclohexene-1-carboxaldehyde, 3-[(acetyloxy)methyl]-2,2,4-trimethyl-(144067-40-3)

Safety Data

• Hazardous Substances Data: 144067-40-3(Hazardous Substances Data)

Upstream product

• 52385-60-1 (3-methyl-2-methylethenyl)-2-buten-1-ol 
• 99978-27-5 2-(α-hydroxy-isopropyl)-3-methyl-crotonic acid ethyl ester 
• 100144-50-1 2-isopropenyl-3-methyl-crotonic acid methyl ester 
• 4412-05-9 2-isopropenyl-3-methyl-crotonic acid 
• 35044-52-1 ethyl 2-acetyl-3-methylbut-2-enoate 
• 144066-82-0 Acetic acid 2-isopropenyl-3-methyl-but-2-enyl ester 
• 107-02-8 acrolein 

Downstream Products

• 216978-17-5 1-Acetoxymethyl-5-(1-hydroxyprop-2-ynyl)-2,6,6-trimethylcyclohex-1-ene 
• 216978-34-6 1-Acetoxymethyl-5-hydroxymethyl-2,6,6-trimethylcyclohex-1-ene 
• 216978-13-1 1-Acetoxymethyl-5-(1,3-dioxolan-2-yl)-2,6,6-trimethylcyclohex-1-ene 
• 216978-73-3 1-Acetoxymethyl-5-(1-hydroxyprop-2-enyl)-2,6,6-trimethylcyclohex-1-ene 
• 144067-41-4 1-Hydroxymethyl-5-(1-hydroxyprop-2-enyl)-2,6,6-trimethylcyclohex-1-ene 
• 216978-37-9 5-tert-Butyldimethylsilyloxymethyl-1-(6-tert-butyldiphenylsilyloxy-1-methoxy-3-methylenehexyl)-2,6,6-trimethylcyclohex-1-ene 
• 216978-36-8 1-[5-(tert-Butyl-dimethyl-silanyloxymethyl)-2,6,6-trimethyl-cyclohex-1-enyl]-6-(tert-butyl-diphenyl-silanyloxy)-3-methylene-hexan-1-ol 
• 216978-42-6 1-{3-[6-(tert-Butyl-diphenyl-silanyloxy)-1-methoxy-3-methylene-hexyl]-2,2,4-trimethyl-cyclohex-3-enyl}-propynone 
• 216978-41-5 1-{3-[6-(tert-Butyl-diphenyl-silanyloxy)-1-methoxy-3-methylene-hexyl]-2,2,4-trimethyl-cyclohex-3-enyl}-prop-2-yn-1-ol 
• 216978-39-1 1-{3-[6-(tert-Butyl-diphenyl-silanyloxy)-1-methoxy-3-methylene-hexyl]-2,2,4-trimethyl-cyclohex-3-enyl}-prop-2-en-1-ol 
• 216978-40-4 1-{3-[6-(tert-Butyl-diphenyl-silanyloxy)-1-methoxy-3-methylene-hexyl]-2,2,4-trimethyl-cyclohex-3-enyl}-propenone 
• 216978-38-0 3-[6-(tert-Butyl-diphenyl-silanyloxy)-1-methoxy-3-methylene-hexyl]-2,2,4-trimethyl-cyclohex-3-enecarbaldehyde 
• 216978-64-2 {3-[6-(tert-Butyl-diphenyl-silanyloxy)-1-methoxy-3-methylene-hexyl]-2,2,4-trimethyl-cyclohex-3-enyl}-methanol 
• 216978-66-4 Toluene-4-sulfonic acid 6-(5-acryloyl-2,6,6-trimethyl-cyclohex-1-enyl)-6-methoxy-4-methylene-hexyl ester 

Relevant articles and documents

The unexpected formation of bicyclo[2.2.1]heptane derivatives by Lewis acid-catalyzed transannular double cyclization

Attempted synthesis of the cyclooctanoid skeleton of taxane molecules, by an intramolecular Lewis acid catalyzed Hosomi-Sakurai cyclization of the allylsilane with the aldehyde moiety in 17, unexpectedly led to the formation of bicyclo[2.2.1]-heptane deri

A tandem radical macrocyclisation-transannular cyclisation approach towards the taxanes

Separate treatment of the iodotrienedione 19 and the iododienynedione 38 with Bu3SnH-AIBN produces the corresponding taxane ring systems 25 (25-30%) and 56 (50-60%) respectively by way of tandem radical macrocyclisation-radical transannular cyc