1440955-95-2Relevant academic research and scientific papers
Copper-catalyzed/promoted cross-coupling of gem -diborylalkanes with nonactivated primary Alkyl halides: An alternative route to alkylboronic esters
Zhang, Zhen-Qi,Yang, Chu-Ting,Liang, Lu-Jun,Xiao, Bin,Lu, Xi,Liu, Jing-Hui,Sun, Yan-Yan,Marder, Todd B.,Fu, Yao
, p. 6342 - 6345 (2014)
The first copper-catalyzed/promoted sp3-C Suzuki-Miyaura coupling reaction of gem-diborylalkanes with nonactivated electrophilic reagents is reported. Not only 1, 1-diborylalkanes but also some other gem-diborylalkanes can be coupled with nonactivated primary alkyl halides, offering a new method for sp3C-sp3C bond formation and, simultaneously, providing a new strategy for the synthesis of alkylboronic esters.
Copper-promoted trifluoromethylation of primary and secondary alkylboronic acids
Xu, Jun,Xiao, Bin,Xie, Chuan-Qi,Luo, Dong-Fen,Liu, Lei,Fu, Yao
supporting information, p. 12551 - 12554 (2013/02/22)
New couple: The Cu-promoted trifluoromethylation of primary and secondary alkylboronic acids with TMSCF3 extends the scope of transition-metal-catalyzed trifluoromethylation reactions to sp 3-hybridized carbon centers. It also repres
