144381-96-4Relevant academic research and scientific papers
Mono- or dichalcogenation of aryl iodide with sulfur or selenium by copper catalyst and aluminum
Taniguchi, Nobukazu
, p. 1687 - 1690 (2007/10/03)
The copper-catalyzed mono- or dichalcogenation of aryl halide with sulfur or selenium can be carried out with the addition of aluminum. This method takes advantage of two properties of both the insertion of copper into the chalcogen-chalcogen bond and the reductive ability of aluminum. Furthermore, the addition of MgCl2 or Na2CO3 enables the selective synthesis of diaryl monochalcogenides or disulfides. Georg Thieme Verlag Stuttgart.
Application of the Hammett Equation to the Electrochemical Oxidation of Diaryl Chalcogenides and Aryl Methyl Chalcogenides
Engman, Lars,Persson, Joachim,Andersson, Carl M.,Berglund, Mats
, p. 1309 - 1313 (2007/10/02)
The electrochemical oxidation of symmetrical 4,4'-disubstituted diaryl selenides and tellurides and 4-substituted aryl methyl sulfides, selenides and tellurides has been studied.Peak oxidation potentials show good correlation with Hammett ?+-va
