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1444-12-8

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1444-12-8 Usage

General Description

Methyl 1-Methyl-1H-indole-4-carboxylate is a chemical compound with the molecular formula C12H13NO2. It is a methyl ester derivative of 1-Methyl-1H-indole-4-carboxylic acid and belongs to the class of organic compounds known as indoles. Methyl 1-Methyl-1H-indole-4-carboxylate is often used in organic synthesis and pharmaceutical research. It has potential applications in the development of new drugs and medications due to its pharmacological properties. Additionally, it may be utilized in the field of chemical research and development as a building block for the synthesis of other complex organic molecules.

Check Digit Verification of cas no

The CAS Registry Mumber 1444-12-8 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,4,4 and 4 respectively; the second part has 2 digits, 1 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 1444-12:
(6*1)+(5*4)+(4*4)+(3*4)+(2*1)+(1*2)=58
58 % 10 = 8
So 1444-12-8 is a valid CAS Registry Number.

1444-12-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name Methyl 1-methyl-1H-indole-4-carboxylate

1.2 Other means of identification

Product number -
Other names methyl 1-methylindole-4-carboxylate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1444-12-8 SDS

1444-12-8Relevant articles and documents

Catalytic Aerobic Dehydrogenatin of N-Heterocycles by N-Hydoxyphthalimide

Chen, Weidong,Tang, Hao,Wang, Weilin,Fu, Qiang,Luo, Junfei

supporting information, p. 3905 - 3911 (2020/08/10)

Catalytic methods for the aerobic dehydrogenation of N-heterocycles are reported. In most cases, indoles are accessed efficiently from indolines using catalytic N-hydroxyphthalimide (NHPI) as the sole additive under air. Further studies revealed an improved catalytic system of NHPI and copper for the preparation of other heteroaromatics, for example quinolines. (Figure presented.).

Electrosynthesis of Dihydropyrano[4,3-b]indoles Based on a Double Oxidative [3+3] Cycloaddition

Choi, Subin,Park, Cheol-Min,Park, Jinhwi,Sim, Jeongwoo,Yu, Eunsoo

supporting information, p. 11886 - 11891 (2020/05/22)

Oxidative [3+3] cycloadditions offer an efficient route for six-membered-ring formation. This approach has been realized based on an electrochemical oxidative coupling of indoles/enamines with active methylene compounds followed by tandem 6π-electrocyclization leading to the synthesis of dihydropyrano[4,3-b]indoles and 2,3-dihydrofurans. The radical–radical cross-coupling of the radical species generated by anodic oxidation combined with the cathodic generation of the base from O2 allows for mild reaction conditions for the synthesis of structurally complex heterocycles.

Detosylative (Deutero)alkylation of Indoles and Phenols with (Deutero)alkoxides

Zhu, Ming-Hui,Yu, Cheng-Long,Feng, Ya-Lan,Usman, Muhammad,Zhong, Dayou,Wang, Xin,Nesnas, Nasri,Liu, Wen-Bo

supporting information, p. 7073 - 7077 (2019/09/30)

An efficient strategy for N/O-(deutero)alkylation of indoles and phenols with alkoxides/alcohols as the alkylation reagents is described. The consecutive detosylation/alkylation transformations feature mild reaction conditions, high ipso-selectivity, and good functional group tolerance (>50 examples). A one-pot selective N-alkylation of unprotected indoles with alcohols and TsCl is also realized. The application of this method is demonstrated by the introduction of isotope-labeled (CD3 and 13CH3) groups using the readily accessible labeled alcohols and the synthesis of pharmaceuticals.

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