1445-83-6

Basic information

• Product Name: 1H-Phosphole, 2,3-dihydro-4-methyl-1-phenyl-
• CAS NO: 1445-83-6
• Molecular Formula: C11H13P
• Molecular Weight: 176.198
• Mol File: 1445-83-6.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 1H-Phosphole, 2,3-dihydro-4-methyl-1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1H-Phosphole, 2,3-dihydro-4-methyl-1-phenyl-(1445-83-6)
• EPA Substance Registry System: 1H-Phosphole, 2,3-dihydro-4-methyl-1-phenyl-(1445-83-6)

Safety Data

• Hazardous Substances Data: 1445-83-6(Hazardous Substances Data)

Upstream product

• 707-61-9 3-Methyl-1-phenyl-2-phospholene 1-oxide 
• 78-79-5 isoprene 
• 1445-83-6 4-methyl-1-phenyl-2,3-dihydro-1H-phosphole 
• 644-97-3 Dichlorophenylphosphine 
• 569680-54-2 (R)-4-Methyl-1-phenyl-2,3-dihydro-phosphole 1-oxide 
• 17786-49-1 1-chloro-4-methyl-1-phenyl-2,3-dihydro-1H-phosphol-1-ium chloride 

Downstream Products

• 149443-46-9 3-Methyl-1-phenyl-4,5-dihydrophosphol 
• 62726-70-9 1r-benzyl-3c-methoxy-3t-methyl-1-phenyl-phospholanium; bromide 
• 62726-70-9 1r-benzyl-3t-methoxy-3c-methyl-1-phenyl-phospholanium; bromide 
• 62726-87-8 3r-methoxy-3-methyl-1-phenyl-phospholane 1t-oxide 
• 62726-87-8 3r-methoxy-3-methyl-1-phenyl-phospholane 1c-oxide 
• 62726-73-2 1-benzyl-3-tert-butoxy-3-methyl-1-phenyl-phospholanium; bromide 
• 62726-72-1 1-benzyl-3-isopropoxy-3-methyl-1-phenyl-phospholanium; bromide 
• 569680-53-1 (S)-4-Methyl-1-phenyl-2,3-dihydro-phosphole 1-oxide 
• 569680-54-2 (R)-4-Methyl-1-phenyl-2,3-dihydro-phosphole 1-oxide 
• 52561-63-4 3-methylene-1-phenyl-phospholane 
• 52561-70-3 3r-tert-butoxy-3-methyl-1t-phenyl-phospholane 
• 52561-70-3 3r-tert-butoxy-3-methyl-1c-phenyl-phospholane 
• 52561-70-3 3-tert-butoxy-3-methyl-1-phenyl-phospholane 
• 52561-69-0 3-isopropoxy-3-methyl-1-phenyl-phospholane 

Relevant articles and documents

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Poly(methylhydrosiloxane) as a green reducing agent in organophosphorus-catalysed amide bond formation

Development of catalytic amide bond formation reactions has been the subject of the intensive investigations in the past decade. Herein we report an efficient organophosphorus-catalysed amidation reaction between unactivated carboxylic acids and amines. Poly(methylhydrosiloxane), a waste product of the silicon industry, is used as an inexpensive and green reducing agent for in situ reduction of phosphine oxide to phosphine. The reported method enables the synthesis of a wide range of secondary and tertiary amides in very good to excellent yields.

Novel Base-Free Catalytic Wittig Reaction for the Synthesis of Highly Functionalized Alkenes

A highly efficient catalyst system for base-free catalytic Wittig reactions has been developed and optimized. Initially, several potential (pre)catalysts as well as different silanes as reducing agents were screened. A system based on a readily available