144542-86-9

Basic information

• Product Name: 1,6-Anhydro-2-O-benzoyl-4-deoxy-4-iodo-β-D-glucopyranose
• Synonyms: 1,6-Anhydro-2-O-benzoyl-4-deoxy-4-iodo-β-D-glucopyranose
• CAS NO: 144542-86-9
• Molecular Weight: 376.148
• Mol File: 144542-86-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,6-Anhydro-2-O-benzoyl-4-deoxy-4-iodo-β-D-glucopyranose(CAS DataBase Reference)
• NIST Chemistry Reference: 1,6-Anhydro-2-O-benzoyl-4-deoxy-4-iodo-β-D-glucopyranose(144542-86-9)
• EPA Substance Registry System: 1,6-Anhydro-2-O-benzoyl-4-deoxy-4-iodo-β-D-glucopyranose(144542-86-9)

Safety Data

• Hazardous Substances Data: 144542-86-9(Hazardous Substances Data)

Upstream product

• 67307-84-0 1,6-Anhydro-2-O-benzoyl-3,4-O-isopropyliden-β-D-galactopyranose 
• 67337-01-3 1,6-Anhydro-2-O-benzoyl-β-D-galactopyranose 
• 52579-97-2 1,6-anhydro-3,4-O-isopropylidene-β-D-galactopyranose 
• 98-88-4 benzoyl chloride 
• 144542-85-8 Benzoic acid (1R,2R,3R,4R,5R)-3-hydroxy-2-trifluoromethanesulfonyloxy-6,8-dioxa-bicyclo[3.2.1]oct-4-yl ester 

Downstream Products

• 220587-72-4 1,6-anhydro-2-O-benzoyl-4-deoxy-3-O-(diphenylhydrazono)acetyl-4-iodo-β-D-glucopyranose 
• 144542-87-0 1,6-Anhydro-2-O-benzoyl-4-deoxy-4-β-D-glucopyranose 

Relevant articles and documents

Reactions of Some Pyranoside Diol Monotriflates with Nucleophiles and Bases

Reaction of pyranoside diol (equatorial) monotriflates with soft, nonbasic nucleophiles is a useful way to make axial heteroatom-substituted and "epimerized" pyranosides, particularly where a fused acetal ring inhibits ring contraction.Among the substrates examined (1,2,3,4,35), only 4 shows a strong tendency to give ring-contracted products.The reaction of 1-3 with more basic nucleophiles (F(1-), t-BuO(1-)) leads to the anhydrosugars 8, 25, and 26, respectively.The SN2 reaction of 35 with tetra n-butylammonium iodide forms the basis for a new synthesis of the Cerny epoxide 32.