144707-83-5Relevant articles and documents
Studies on the silylation reaction of α,β-epoxy esters synthesized by Darzen's condensation reaction
Bolourtchian, Mohammed,Mamaghani, Manouchehr,Badrian, Abed
, p. 2545 - 2550 (2003)
Me3SiCl/Mg in HMPA was used for silylation of α,β-epoxy esters resulting in the corresponding β-silylated esters in a one pot reaction with reasonable yields.
Magnesium-induced regiospecific C-silylation of suitably substituted enoates and dienoates
Kundu, Pintu K.,Ghosh, Sunil K.
experimental part, p. 8562 - 8568 (2010/11/05)
The β-aryl-β-silyl and β,β-disilyl propionates have been synthesized from cinnamates and β-silyl acrylates by a regiospecific reductive C-silylation using Mg/silyl chloride/DMF system at room temperature. These reductive C-silylation conditions have also been applied to δ-aryl substituted dienoates wherein silylation took place at the δ-position leading to the synthesis of single regioisomeric allylsilanes with very high stereoselectivity.
Electroreductive silylation of activated olefins using a reactive metal anode
Ohno,Nakahiro,Sanemitsu,Hirashima,Nishiguchi
, p. 5515 - 5516 (2007/10/02)
Electroreductive silylation of α, β-unsaturated esters, nitriles and ketones in the presence of Me3SiCl using a reactive metal anode (Mg, Zn, Al) in an undivided cell afforded the corresponding β-silyl compounds offering a valuable method for introduction of a silyl group into activated olefins.
