144707-84-6Relevant articles and documents
Electroreductive silylation of activated olefins using a reactive metal anode
Ohno,Nakahiro,Sanemitsu,Hirashima,Nishiguchi
, p. 5515 - 5516 (1992)
Electroreductive silylation of α, β-unsaturated esters, nitriles and ketones in the presence of Me3SiCl using a reactive metal anode (Mg, Zn, Al) in an undivided cell afforded the corresponding β-silyl compounds offering a valuable method for introduction of a silyl group into activated olefins.
Catalyst-Free and Solvent-Controlled Reductive Coupling of Activated Vinyl Triflates with Chlorotrimethylsilane by Magnesium Metal and Its Synthetic Application
Maekawa, Hirofumi,Noda, Katsuaki,Kuramochi, Keisuke,Zhang, Tianyuan
supporting information, p. 1953 - 1956 (2018/04/16)
Vinylsilanes were directly prepared from the corresponding vinyl triflates under magnesium-promoted reductive conditions in THF with no transition metal catalyst, and gem-bis-silylated compounds were obtained in NMP. Investigation of the redox potential o