144757-84-6Relevant articles and documents
A Tf2O-Promoted Synthesis of Functionalized Quinolines from Ketoximes and Alkynes
Zheng, Weiping,Yang, Weiguang,Luo, Dongping,Min, Lin,Wang, Xinyan,Hu, Yuefei
supporting information, p. 1995 - 1999 (2019/03/13)
A new general synthesis of quinolines was developed from ketoximes and alkynes in the presence of Tf2O. It offered the first direct synthesis of quinolines by using the nitrilium salts generated in situ from a Tf2O-promoted Beckmann rearrangement of ketoximes under very easy conditions. (Figure presented.).
On the reaction of N-arylnitrilium salts with acetylenes: Synthesis of substituted quinolines
Al-Talib,Jochims,Wang,Hamed,Ismail
, p. 875 - 878 (2007/10/02)
Quinolinium salts 3 are obtained from the reaction of N-arylnitrilium salts 1 with acetylenes 2. With aqueous base the salts 3 are transformed into the corresponding quinolines 4.