1714-50-7

Basic information

• Product Name: N-[Bis(4-chlorophenyl)methylene]hydroxylamine
• Synonyms: 4,4'-Dichlorobenzophenone oxime;N-[Bis(4-chlorophenyl)methylene]hydroxylamine;α-(4-Chlorophenyl)-N-hydroxy-4-chlorobenzenemethanimine
• CAS NO: 1714-50-7
• Molecular Formula: C₁₃H₉Cl₂NO
• Molecular Weight: 266.12
• Mol File: 1714-50-7.mol
• Article Data: 20

Chemical Properties

• Boiling Point: 388.4°C at 760 mmHg
• Flash Point: 188.7°C
• Appearance: /
• Density: 1.29g/cm³
• Vapor Pressure: 9.94E-07mmHg at 25°C
• Refractive Index: 1.601
• CAS DataBase Reference: N-[Bis(4-chlorophenyl)methylene]hydroxylamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-[Bis(4-chlorophenyl)methylene]hydroxylamine(1714-50-7)
• EPA Substance Registry System: N-[Bis(4-chlorophenyl)methylene]hydroxylamine(1714-50-7)

Safety Data

• Hazardous Substances Data: 1714-50-7(Hazardous Substances Data)

Usage

InChI:InChI=1/C13H9Cl2NO/c14-11-5-1-9(2-6-11)13(16-17)10-3-7-12(15)8-4-10/h1-8,17H

Upstream product

• 90-98-2 4,4'-Dichlorobenzophenone 
• 108-90-7 chlorobenzene 
• 134-85-0 4-chlorobenzophenone 
• 92977-37-2 2-tert-Butyl-3,3-bis-(4-chloro-phenyl)-oxaziridine 

Downstream Products

• 138761-34-9 C₁₆H₁₇Cl₂NOSi 
• 68655-68-5 4-[di-(4-chlorophenyl)methyleneamino-oxy]butyric acid benzylamine salt 
• 1233720-13-2 diethyl 2-((4-chlorophenyl)(4-chlorophenylamino)methylene)malonate 
• 144757-84-6 6-chloro-2-(4-chlorophenyl)-3,4-diphenylquinoline 
• 1101206-97-6 C₁₆H₁₃Cl₂NO 
• 68655-56-1 ethyl di-(4-chlorophenyl)methyleneamino-oxyacetate 
• 30752-60-4 C₁₆H₁₄Cl₂N₂OS 
• 71338-40-4 4,4'-dichlorophenyl-methyl-isocyanate 
• 68655-69-6 di-(4-chlorophenyl)methyleneamino-oxyacetamide 

Relevant articles and documents

Rhodium(iii)-catalyzed asymmetric [4+1] spiroannulations of: O -pivaloyl oximes with α-diazo compounds

Chiral RhIII catalysts can catalyze the asymmetric [4+1] spiroannulation of O-pivaloyl oximes with α-diazo homophthalimides under redox-neutral and acid/base-neutral conditions, leading to formation of chiral spirocyclic imines as a result of C-H activation and N-O cleavage. The reaction proceeded with high efficiency and features broad substrate scope, mild reaction conditions, and high to excellent enantioselectivities. This journal is

Vilsmeier-Haack reagent mediated synthetic transformations with an immobilized iridium complex photoredox catalyst

An immobilized iridium complex photocatalyst Ir(ppy)2(PDVB-py) was synthesized by immobilization of the iridium complex onto the nanoporous vinylpyridine-divinylbenzene copolymer (PDVB-py). Its application for the synthesis of amides, nitriles, and anhydrides was reported via reactions under the action of the visible-light-driven in situ generated Vilsmeier-Haack reagent from CBr4 in DMF. The results showed that this heterogeneous photocatalyst has extremely high activity and excellent stability to be recycled five times.

Pt-catalyzed O-silylation of oximes by tri-substituted organosilanes

Silylated derivatives of oximes are important intermediates in organic synthesis, and have found application in the preparation of various nitrogen containing compounds including nitriles, amines, nitrones, and hydroxylamines. An efficient method for the