1448718-36-2

Upstream product

• 77758-51-1 methyl hex-5-ynoate 
• 100-52-7 benzaldehyde 
• 521950-37-8 (E)-6-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)hex-5-enoic acid methyl ester 

Relevant academic research and scientific papers

Enantioselective synthesis of anti homoallylic alcohols from terminal alkynes and aldehydes based on concomitant use of a cationic iridium complex and a chiral phosphoric acid

We report a highly diastereo- and enantioselective synthesis of anti homoallylic alcohols from terminal alkynes via (E)-1-alkenylboronates based upon two catalytic reactions: a cationic iridium complex-catalyzed olefin transposition of (E)-1-alkenylboronates and a chiral phosphoric acid-catalyzed allylation reaction of aldehydes.