1448901-07-2

Basic information

• Product Name: 4,6-di-p-tolyl-2H-pyran-2-one
• Synonyms: 4,6-di-p-tolyl-2H-pyran-2-one
• CAS NO: 1448901-07-2
• Molecular Weight: 276.335
• Mol File: 1448901-07-2.mol

Chemical Properties

• CAS DataBase Reference: 4,6-di-p-tolyl-2H-pyran-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: 4,6-di-p-tolyl-2H-pyran-2-one(1448901-07-2)
• EPA Substance Registry System: 4,6-di-p-tolyl-2H-pyran-2-one(1448901-07-2)

Safety Data

• Hazardous Substances Data: 1448901-07-2(Hazardous Substances Data)

Upstream product

• 124-38-9 carbon dioxide 
• 36201-04-4 1,3-di-p-tolylbut-2-en-1-one 
• 766-97-2 4-n-methylphenylacetylene 

Relevant articles and documents

Synthesis of α-pyrones by catalytic oxidative coupling of terminal alkynes and carbon dioxide

The use of the complex [(dippe)Ni(μ-H)]2(1) as a catalyst precursor (10?mol%) in the presence of a variety of terminal alkynes and CO2allowed the production of substituted α–pyrones. This reaction occurs using relatively mild conditions (50?°C, 150 psi of CO2) with good to modest yields, depending on the nature of the substituents in the corresponding alkyne. The produced α–pyrones were characterized by different analytical methods and spectroscopic techniques.

Carboxylative cyclization of substituted propenyl ketones using CO2: Transition-metal-free synthesis of Α-pyrones

Carbon dioxide is a green carboxylative reagent due to its non-toxic and renewable properties. Described herein is a carboxylative cyclization of substituted 1-propenyl ketones via γ-carboxylation using CO2, which provides an efficient, transit

Diversity-oriented general protocol for the synthesis of privileged oxygen scaffolds: Pyrones, coumarins, benzocoumarins and naphthocoumarins

A new general methodology for the synthesis of various functionalized privileged oxygen heterocyclic scaffolds, viz. pyrones, coumarins, and benzannulated coumarins, is developed. The synthesis proceeds through carbanion-induced ring transformation of lactones with various methylene carbonyl compounds followed by DDQ-mediated unprecedented oxidative cleavage of oxaylidenes intermediates. Studies of the mechanism of the conversions of oxaylidene intermediates into corresponding carbonyl compounds in the presence of DDQ revealed that the reactions took place via the formation of a Michael adduct instead of an intermolecular charge transfer complex. The methodology offers the fabrication of diverse privileged scaffolds with tolerance for many functional groups onto the oxygen heterocyclic molecular framework.